MPI-DING reference glasses for in situ microanalysis: New reference values for element concentrations and isotope ratios
We present new analytical data of major and trace elements for the geological MPI-DING glasses KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, BM90/21-G, T1-G, and ATHO-G. Different analytical methods were used to obtain a large spectrum of major and trace element data, in particular, EPMA, SIMS, LA-ICPMS, and isotope dilution by TIMS and ICPMS. Altogether, more than 60 qualified geochemical laboratories worldwide contributed to the analyses, allowing us to present new reference and information values and their uncertainties (at 95% confidence level) for up to 74 elements. We complied with the recommendations for the certification of geological reference materials by the International Associ…
Determination of Reference Values for NIST SRM 610-617 Glasses Following ISO Guidelines
We present new reference values for the NIST SRM 610–617 glasses following ISO guidelines and the International Association of Geoanalysts’ protocol. Uncertainties at the 95% confidence level (CL) have been determined for bulk- and micro-analytical purposes. In contrast to former compilation procedures, this approach delivers data that consider present-day requirements of data quality. New analytical data and the nearly complete data set of the GeoReM database were used for this study. Data quality was checked by the application of the Horwitz function and by a careful investigation of analytical procedures. We have determined quantitatively possible element inhomogeneities using different …
Ultrapotassic Mafic Rocks as Geochemical Proxies for Post-collisional Dynamics of Orogenic Lithospheric Mantle: the Case of Southwestern Anatolia, Turkey
High-Mg ultrapotassic volcanic rock occurrences of lamproitic affinity are exposed in southwestern Anatolia, mostly within the Menderes Massif. From north to south the lamproitic volcanism shows increasingly younger ages ranging from 20 to 4 Ma. Volcanism is contemporaneous with more voluminous shoshonitic, high-K calc-alkaline, and ultrapotassic magmatic activity in the Simav-Selendi, Usak, Kirka, Koroglu, Afyon and Isparta-Golcuk areas. The southward decrease in the age of the volcanism correlates with changes in geochemical composition, particularly a decrease in Sr-87/Sr-86, Pb-207/Pb-204, Zr/Nb and Th/Nb, and an increase in Nd-143/Nd-144, Hf-176/Hf-177, Pb-206/Pb-204, Pb-208/Pb-204 and…
Between carbonatite and lamproite - Diamondiferous Torngat ultramafic lamprophyres formed by carbonate-fluxed melting of cratonic MARID-type metasomes
Abstract New U–Pb perovskite ages reveal that diamondiferous ultramafic lamprophyre magmas erupted through the Archean crust of northern Labrador and Quebec (eastern Canada) between ca. 610 and 565 Ma, a period of strong rifting activity throughout contiguous Laurentia and Baltica. The observed Torngat carbonate-rich aillikite/carbonatite and carbonate-poor mela-aillikite dyke varieties show a large spread in Sr–Nd–Hf–Pb isotope ratios with pronounced correlations between isotope systems. An isotopically depleted component is identified solely within aillikites (87Sr/86Sri = 0.70323–0.70377; eNdi = +1.2–+1.8; eHfi = +1.4–+3.5; 206Pb/204Pbi = 18.2–18.5), whereas some aillikites and all mela-…
FeMnOx-1: A new microanalytical reference material for the investigation of Mn–Fe rich geological samples
Suitable Mn-Fe rich microanalytical reference materials (MRMs) as calibration material for laser ablation-inductively coupled plasma mass spectrometry (LA-ICPMS) have not been available. The United States Geological Survey (USGS) in collaboration with the Max Planck Institute for Chemistry has prepared a synthetic MRM, FeMnOx-1, with elevated mass fractions of MnO (25 g/100 g), Fe2O3 (8.5 g/100 g) and high mass fractions of 25 trace elements varying between 200 and 5000 mg/kg. This new MRM has been designed as calibration material for a wide range of different Mn-Fe deposits, such as desert/rock varnish, ocean crusts and nodules as well as Mn accumulations in soils and lakes. Small-scale an…
Melt evolution beneath a rifted craton edge: 40Ar/39Ar geochronology and Sr-Nd-Hf-Pb isotope systematics of primitive alkaline basalts and lamprophyres from the SW Baltic Shield
A new high-precision Ar-40/Ar-39 anorthoclase feldspar age of 176.7 +/- 0.5 Ma (2-sigma) reveals that small-volume alkaline basaltic magmatism occurred at the rifted SW margin of the Baltic Shield in Scania (southern Sweden), at a time of global plate reorganization associated with the inception of Pangea supercontinent break-up. Our combined elemental and Sr-Nd-Hf-Pb isotope dataset for representative basanite and nephelinite samples (>8 wt.% MgO) from 16 subvolcanic necks of the 30 by 40 km large Jurassic volcanic field suggests magma derivation from a moderately depleted mantle source (Sr-87/(86)Sri = 0.7034-0.7048; epsilon Nd-i = +4.4 to +5.2; epsilon Hf-i = +4.7 to +8.1; Pb-206/(204)Pb…
Craton reactivation on the Labrador Sea margins: 40Ar/39Ar age and Sr–Nd–Hf–Pb isotope constraints from alkaline and carbonatite intrusives
Abstract The once-contiguous North Atlantic craton (NAC) is crosscut by the Labrador Sea that opened during the Early Cenozoic after extensive Mesozoic continental rifting and removal of cratonic mantle. This large-scale structural change within the cratonic lithosphere was followed at about 150 Ma by the cessation of ultrapotassic and potassic-to-carbonatitic magma production, which had prevailed throughout much of the NAC history. At Aillik Bay, a sequence of olivine lamproites (1374.2 ± 4.2 Ma, 2σ), aillikites/carbonatites (590–555 Ma), and nephelinites (141.6 ± 1.0 Ma, 2σ) erupted through the southern NAC edge on the present-day Labrador Sea margin. Links between these alkaline magma ty…
Hf isotope compositions of Mediterranean lamproites: Mixing of melts from asthenosphere and crustally contaminated mantle lithosphere
Abstract Mediterranean lamproites from Spain, Italy, Serbia and Macedonia are mantle-derived ultrapotassic volcanic rocks that occur exclusively in postcollisional, extension-related geodynamic settings within the Alpine–Himalaya orogenic belt. Previous studies inferred them to be multi-component melts, originating by mixing of several mantle end-members: (1) provenance-controlled crust-contaminated mantle component(s), (2) an ultra-depleted mantle component, and (3) a component ultimately derived from the convecting mantle. Hf isotope ratios of Mediterranean lamproites reported here cover a large range of eHf values from 0 to −15, for less variable eNd −2 to −13, providing further evidence…