0000000000282782
AUTHOR
Cristina Carbone
New insights on secondary minerals from Italian sulfuric acid caves
Sulfuric acid minerals are important clues to identify the speleogenetic phases of hypogene caves. Italy hosts ~25% of the known worldwide sulfuric acid speleogenetic (SAS) systems, including the famous well-studied Frasassi, Monte Cucco, and Acquasanta Terme caves. Nevertheless, other underground environments have been analyzed, and interesting mineralogical assemblages were found associated with peculiar geomorphological features such as cupolas, replacement pockets, feeders, sulfuric notches, and sub-horizontal levels. In this paper, we focused on 15 cave systems located along the Apennine Chain, in Apulia, in Sicily, and in Sardinia, where copious SAS minerals were observed. Some of the…
Secondary minerals from salt caves in the Atacama Desert (Chile): a hyperarid and hypersaline environment with potential analogies to the Martian subsurface
Over the past 15 years several expeditions by French, American and especially Italian cavers have unveiled over 50 caves in the Cordillera de la Sal (Atacama Desert, Northern Chile). Many of these caves contain a variety of speleothems and minerals, some of which have rarely been observed within karst systems. Most of the secondary deposits in these caves are composed of halite, but also other halide, carbonate, sulphate, nitrate, phosphate, and silicate minerals have been found. Among the sixteen cave mineral species recognized, atacamite, darapskite, blödite, leonite, anhydrite, and especially antarcticite are worth mentioning. In one of the samples an unknown Ca-Sr-bearing chloride miner…
Guano-related phosphate-rich minerals in European caves
International audience; Guano is a typical deposit found in caves derived from the excretions of bats and in minor cases of birds. These organic deposits decompose and form a series of acid fluids and gases that can interact with the minerals, sediments, and rocks present in the cave. Over sixty phosphates are known and described from caves, but guano decay also often leads to the formation of nitrates and sulfates. In this study twenty-two European caves were investigated for their guano-related secondary minerals. Using various analytical techniques, seventeen phosphates, along with one sulfate (gypsum), were recognized as secondary products of guano decay. Among those minerals, some are …
Secondary minerals from halite caves in the Atacama Desert (Chile)
In the past 15 years several expeditions by French, American and especially Italian cavers have surveyed over 15 km of salt cave passages in the Cordillera de la Sal, close to San Pedro de Atacama village (Atacama Desert, Northern Chile). Over 50 caves have been explored up to now at an elevation around 2,500 m asl. These karst systems are characterized by in-cave temperature of around 17 °C and a relative humidity always very low, with a maximum of 15%. This extreme aridity is due to the severe conditions of the area with only a couple millimeters annual rainfall and several years without rain. Currently the rare precipitation events are enough to allow the dissolution of the salt rock and…