0000000000284969
AUTHOR
Rita Berzina
Manufacturing, structure and properties of recycled polyethylene terephthalate /liquid crystal polymer/montmorillonite clay nanocomposites
Polyethylene terephthalate (PET)/liquid crystal polymer (LCP)/monthmorillonite clay (MMT) compositions were obtained by melt mixing. Their mechanical, structural, rheological and thermal properties were investigated.
Elasticity and long-term behavior of recycled polyethylene terephthalate (rPET)/montmorillonite (MMT) composites
Abstract Recycled polyethylene terephthalate (rPET) nanocomposites with various amounts of montmorillonite clay (MMT) have been manufactured by using twin screw extrusion. By rising MMT weight content Wf up to 1 wt.% it is possible to increase yield strength and ultimate strength of the composite by 17% and 27% respectively in comparison to neat rPET. Introduction of MMT in the rPET leads also to considerable increase of the modulus of elasticity E. Relationship E(Wf), however, is non-linear and is characterized by slow-down in E growth along with increasing MMT content. At low nanofiller content experimental results are sufficiently well described by using the method of Mori–Tanaka and the…
Recycled Polycarbonate Based Nanocomposites
Post-consumer polycarbonate (RPC) blends with various amounts (5, 10, 30 wt. %) of ethylene vinyl acetate copolymer (EVAc) are investigated as potential nanocomposite matrices. At EVAc weight content of 10 wt.% maximum tensile strength σM and impact strength AI increase is observed in comparison to neat RPC. Addition of EVAc, however, reduces resistance to creep as well as decrease thermal stability of the investigated compositions. Addition of montmorillonite nanoclay (MMT), however, allows increase modulus of elasticity E and yield strength σY of the investigated RPC blend with 10 wt. % of EVAc. Besides it creep resistance and thermal resistance of the investigated system is increased to …
The effect of introduction of montmorillonite clay (MMT) on the elastic properties of polycarbonate (PC) composition with acrylonitrile-butadiene styrene (ABS)
Abstract Polycarbonate (PC)/acrylonitrile–butadiene–styrene terpolymer (ABS)/montmorillonite (MMT) nanocomposites have been obtained by melt compounding in a twin-screw extruder. Structural and elastic properties have been characterized. The theoretical analysis of the elastic properties of PC/ABS/MMT composite with a widely varied number of elementary layers in clay filler particles has been performed in order to estimate the influence of the degree of exfoliation of particles on the effect of reinforcement of the material. Results of the theoretical analysis have been compared with the experimental data about the effects of unmodified and two types of organically modified montmorillonite …
Simple Solution for Single Final Vial Filling of Ga-68 Radiopharmaceuticals in One Hot Cell Isolator at Small-Scale Radiopharmacy Laboratories under Aseptic Conditions
A simple solution for fulfilling biosafety and national drug agency demands of radiation and biosafety during Ga-68 radionuclide containing radiopharmaceutical production (RP) by small scale laboratories has been demonstrated based on a novel sterile seal concept of multi-layer bag system prototype. These mid-and inner enclosures of the prototype with vial inside were sterilized by 50 kGy of gamma radiation. The microbial safety validation based on two-week testing confirmed successful sterilization of the sealing bags with vails. The analysis of physicochemical properties, namely mechanical properties, gel fraction studies revealed that sterilization did not cause any undesired changes in …
Recycled Polycarbonate Blend as Matrix for Development of Polymer Nanocomposite
Summary: Secondary polycarbonate (SPC) is modified with various amounts (5, 10, 30 wt%) of ethylene vinyl acetate copolymer (EVAc) in order to reduce its brittleness. It is observed that at optimal EVAc weight content maximum tensile strength σM and impact strength AI increse by 14% (ωEVAc = 5 wt%) and 450% (ωEVAc = 10 wt%) in comparison to neat SPC, respectively. Addition of montmorillonite nanoclay (MMT) allowed further increase of elastic modulus E, strength and creep resistance of the investigated SPC blend with 10 wt% of EVAc.