0000000000285786
AUTHOR
Gustavo Garzón
Retrieval of absolute SO<sub>2</sub> column amounts from scattered-light spectra – Implications for the evaluation of data from automated DOAS Networks
Abstract. Scanning Differential Optical Absorption Spectroscopy (DOAS) networks using scattered solar radiation have become an increasingly important tool for monitoring volcanic sulphur dioxide (SO2) emissions. In order to get absolute column densities (CDs), the DOAS evaluation requires a Fraunhofer Reference Spectrum (FRS) that is free of absorption structures of the trace gas of interest. At volcanoes, this requirement can be formulated in a weaker form, if there is a plume free viewing direction within the spectra of a scan through the complete sky. In this case, it is possible to use a specific viewing direction (e.g. zenith) as FRS and correcting for possible plume contamination in t…
Geochemical processes assessed by Rare Earth Elements fractionation at "Laguna Verde" acidic-sulphate crater lake (Azufral volcano, Colombia)
Abstract The geochemical behaviour of major elements, Fe, Al, Mn, and Rare Earth Elements (REE) was investigated in the “Laguna Verde” acidic crater lake of Azufral volcano (Colombia). The cold lake water (T close to 10 °C) is sulphate-dominated, due to absorption and oxidation of H2S (pH 2.1–2.7, Eh 196–260 mV), and Na-enriched (Total Dissolved Solids 0.79 g L−1). The total amount of REE dissolved in the lake ranges from 3.3 to 9.1 ppb. The REE patterns normalized to the local rocks show a Light Rare Earth Elements (LREE) depletion quite constant in the 15 samples. Similar patterns were already found in the acidic sulphate springs of Nevado del Ruiz volcano-hydrothermal system, caused by t…