Spin dynamics in the single-ion magnet [Er(W5O18)2]9−

In this work we present a detailed NMR and ${\ensuremath{\mu}}^{+}\mathrm{SR}$ investigation of the spin dynamics in the new hydrated sodium salt containing the single-ion magnet ${[\mathrm{Er}{({\mathrm{W}}_{5}{\mathrm{O}}_{18})}_{2}]}^{9\ensuremath{-}}$. The $^{1}\mathrm{H}\phantom{\rule{0.16em}{0ex}}\mathrm{NMR}$ absorption spectra at various applied magnetic fields present a line broadening on decreasing temperature which indicates a progressive spin freezing of the single-molecule magnetic moments. The onset of quasistatic local magnetic fields, due to spin freezing, is observed also in the muon relaxation curves at low temperature. Both techniques yield a local field distribution of t…