0000000000292130
AUTHOR
B. Bernhardt
Field-portable Mössbauer spectroscopy on Earth, the Moon, Mars, and beyond
ABSTRACT Iron occurs naturally as Fe 2+ , Fe 3+ , and, to a lesser extent, as Fe 0 . Many fundamental (bio)geochemical processes are based on redox cycling between these oxidation states. Mossbauer spectroscopy provides quantitative information about the distribution of Fe among its oxidation states, identification of Fe-bearing phases, and relative distribution of Fe among those phases. Portable, miniaturised Mossbauer spectrometers were developed for NASA9s Mars Exploration Rovers (in operation since 2004) and provide a means for non-destructive, in-situ field investigations. On Mars, these instruments provided evidence for aqueous activity with implications for habitability, were applied…
Surface Analysis in Archaeology Using the Miniaturized Mössbauer Spectrometer MIMOS II
A miniaturized Mossbauer spectrometer (MIMOS II) which was designed and constructed for extraterrestrial applications, such as iron-containing rock and soil analysis on the planet Mars, has been employed to investigate the iron-containing constituents in the paintings of a Lekythos Greek vase. Greek pottery is commonly painted with black figures. The Mossbauer backscattering spectra recorded with MIMOS II at room temperature show that the hand-painted black figures contain hematite.
Mineralogy at Gusev Crater from the Mössbauer spectrometer on the Spirit Rover.
Mössbauer spectra measured on Mars by the Spirit rover during the primary mission are characterized by two ferrous iron doublets (olivine and probably pyroxene) and a ferric iron doublet (tentatively associated to nanophase ferric iron oxide). Two sextets resulting from nonstoichiometric magnetite are also present, except for a coating on the rock Mazatzal, where a hematite-like sextet is present. Greater proportions of ferric-bearing phases are associated with undisturbed soils and rock surfaces as compared to fresh rock surfaces exposed by grinding. The ubiquitous presence of olivine in soil suggests that physical rather than chemical weathering processes currently dominate at Gusev crat…
Mauna Kea, Hawaii, as an Analog Site for Future Planetary Resource Exploration: Results from the 2010 ILSO-ISRU Field-Testing Campaign
Within the framework of the International Lunar Surface Operation - In-Situ Resource Utilization Analogue Test held on January 27 - February 11, 2010 on the Mauna Kea volcano in Hawaii, a number of scientific instrument teams collaborated to characterize the field site and test instrument capabilities outside laboratory environments. In this paper, we provide a geological setting for this new field-test site, a description of the instruments that were tested during the 2010 ILSO-ISRU field campaign, and a short discussion for each instrument about the validity and use of the results obtained during the test. These results will form a catalogue that may serve as reference for future test cam…
Robotic Exploration of Planetary Surfaces – Rover Technologies Developed for Space Exploration
Mobility is a key feature for any science mission and for space exploration in general. Missions with mobile systems provide a much wider spectrum of outcomes by employing a higher number of samples within an increased area of exploration. The additional degree of freedom of a rover in comparison to a lander or even a robotic arm allows the mission to be flexibly adapted to the landing site as it is encountered.
Jarosite and hematite at Meridiani Planum from Opportunity's Mossbauer Spectrometer.
Mössbauer spectra measured by the Opportunity rover revealed four mineralogical components in Meridiani Planum at Eagle crater: jarosite- and hematite-rich outcrop, hematite-rich soil, olivine-bearing basaltic soil, and a pyroxene-bearing basaltic rock (Bounce rock). Spherules, interpreted to be concretions, are hematite-rich and dispersed throughout the outcrop. Hematitic soils both within and outside Eagle crater are dominated by spherules and their fragments. Olivine-bearing basaltic soil is present throughout the region. Bounce rock is probably an impact erratic. Because jarosite is a hydroxide sulfate mineral, its presence at Meridiani Planum is mineralogical evidence for aqueous proc…
FIDO science payload simulating the Athena Payload
[1] The Jet Propulsion Laboratory's Field Integrated Development and Operations rover (FIDO) emulates and tests operational rover capabilities for advanced Mars rover missions, such as those originally planned for the Mars Surveyor 2001 Rover and currently planned for the Athena Payload on the Mars Exploration Rovers scheduled for launch in 2003. This paper describes FIDO's science instrument payload, which is fully integrated with rover hardware and software. Remote science teams visualize instrument suite data and generate FIDO commands using the Web Interface for Telescience. FIDO's instrument suite has been used in terrestrial laboratory and field tests to simulate Mars operations, to t…
The miniaturised Mössbauer spectrometer MIMOS IIA: Increased sensitivity and new capability for elemental analysis
The Miniaturised Mossbauer Spectrometers MIMOS II on board the two Mars Exploration Rovers (MER) have now been collecting valuable scientific data for more than five years. Mossbauer Spectrometers are part of two future missions: Phobos Grunt (Russian Space Agency) and a joint ESA—NASA Rover in 2018. The new advanced MIMOS IIA instrument described in this paper uses Silicon Drift Detectors (SDD) allowing also X-ray fluorescence chemical analysis (XRF) simultaneously to Mossbauer acquisitions. This paper highlights the features and technological improvements of the new spectrometer MIMOS IIA.
Rock paintings from Minas Gerais, Brasil, investigated by in-situ Mössbauer spectroscopy
The archaeological site of Santana do Riacho is located at about 90 km northeastern of Belo Horizonte, in the “Serra do Cipo” region. The recent development of a miniaturised Mossbauer spectrometer opened the possibility of making in-situ measurements of the rock paitings, and the results of such pioneer work is presented in this contribution. The spectrometer MIMOS II operates in backscattering geometry measuring the scattered 14.41 keV Mossbauer radiation and the 6.4 keV Fe X-rays. The dimensions of the whole instrument are approximately 110 mm (long) × 80 mm (diameter). The paintings were selected based on their colours and apparent thickness, and six spots were measured. The analysis of…
Mössbauer mineralogy of rock, soil, and dust at Gusev crater, Mars: Spirit's journey through weakly altered olivine basalt on the plains and pervasively altered basalt in the Columbia Hills
The Moessbauer spectrometer on Spirit measured the oxidation state of Fe, identified Fe-bearing phases, and measured relative abundances of Fe among those phases for surface materials on the plains and in the Columbia Hills of Gusev crater. Eight Fe-bearing phases were identified: olivine, pyroxene, ilmenite, magnetite, nanophase ferric oxide (npOx), hematite, goethite, and a Fe(3+)-sulfate. Adirondack basaltic rocks on the plains are nearly unaltered (Fe(3+)/Fe(sub T) Px), and minor npOx and magnetite. Columbia Hills basaltic rocks are nearly unaltered (Peace and Backstay), moderately altered (WoolyPatch, Wishstone, and Keystone), and pervasively altered (e.g., Clovis, Uchben, Watchtower, …
APXS and MIMOS IIA: Planetary and terrestrial applications
Both Alpha Particle X-ray Spectrometer (APXS) and the Miniaturized Moessbauer Spectrometer (MIMOS II) have shown their performances in space missions and terrestrial applications. Taking advantage of the challenges of space missions both instruments have become very powerful tools, even small in mass and dimensions.
Background radiation effects and hazards in planetary instrumentation
Recent and proposed future planetary missions are becoming increasingly concerned with detailed geochemical assessment, often in a bid to ascertain the presence of water and life supporting geochemical systems. The instruments involved may use some kind of radioactive source, e.g. X-ray fluorescence spectrometry, Mossbauer spectrometry, neutron scattering. Having radioactive sources on a lander/rover poses various potential problems, in regard to both safety to personnel involved in the building of the instrument and to radiation effects on spacecraft structure and on other instruments. Indeed background radiation effects from one instrument may dominate measurements in another resulting in…
Athena MIMOS II Mössbauer spectrometer investigation
[1] Mossbauer spectroscopy is a powerful tool for quantitative mineralogical analysis of Fe-bearing materials. The miniature Mossbauer spectrometer MIMOS II is a component of the Athena science payload launched to Mars in 2003 on both Mars Exploration Rover missions. The instrument has two major components: (1) a rover-based electronics board that contains power supplies, a dedicated central processing unit, memory, and associated support electronics and (2) a sensor head that is mounted at the end of the instrument deployment device (IDD) for placement of the instrument in physical contact with soil and rock. The velocity transducer operates at a nominal frequency of ∼25 Hz and is equipped…
Mössbauer mineralogy of rock, soil, and dust at Meridiani Planum, Mars: Opportunity's journey across sulfate-rich outcrop, basaltic sand and dust, and hematite lag deposits
Additonal co-authors: P Gutlich, E Kankeleit, T McCoy, DW Mittlefehldt, F Renz, ME Schmidt, B Zubkov, SW Squyres, RE Arvidson