Effects of Oxygen Plasma on the Chemical, Light-Emitting, and Electrical-Transport Properties of Inorganic and Hybrid Lead Bromide Perovskite Nanocrystal Films
We show that oxygen plasma affects in different ways the structural, chemical, optical, and electrical properties of methylammonium and cesium lead bromide nanocrystals. Hybrid organic–inorganic nanocrystals were severely and quickly degraded by oxygen plasma at 50 W. Their photoluminescence was quenched with almost 100% loss of the initial quantum yield, which is linked to decomposition of the nanocrystals. Inorganic nanocrystals were more resistant to oxygen plasma in the same conditions. Despite a moderate loss of photoluminescence and electrical conductivity, oxygen plasma had a positive impact, removing unbound ligands and resulting in more ohmic behavior of the film. This paves the wa…
Designing Precoding and Receive Matrices for Interference Alignment in MIMO Interference Channels
Interference is a key bottleneck in wireless communication systems. Interference alignment is a management technique that align interference from other transmitters in the least possibly dimension subspace at each receiver and provides the remaining dimensions for free interference signal. An uncoordinated interference is an example of interference which cannot be aligned coordinately with interference from coordinated part; consequently, the performance of interference alignment approaches are degraded. In this paper, we propose a rank minimization method to enhance the performance of interference alignment in the presence of uncoordinated interference sources. Firstly, to obtain higher mu…
In situ transmission electron microscopy study of electron beam-induced transformations in colloidal cesium lead halide perovskite nanocrystals
An increasing number of studies have recently reported the rapid degradation of hybrid and all-inorganic lead halide perovskite nanocrystals under electron beam irradiation in the transmission electron microscope, with the formation of nanometer size, high contrast particles. The nature of these nanoparticles and the involved transformations in the perovskite nanocrystals are still a matter of debate. Herein, we have studied the effects of high energy (80/200 keV) electron irradiation on colloidal cesium lead bromide (CsPbBr3) nanocrystals with different shapes and sizes, especially 3 nm thick nanosheets, a morphology that facilitated the analysis of the various ongoing processes. Our resul…
Towards proactive context-aware self-healing for 5G networks
In this paper, we suggest a new research direction and a future vision for Self-Healing (SH) in Self-Organizing Networks (SONs). The problem we wish to solve is that traditional SH solutions may not be sufficient for the future needs of cellular network management because of their reactive nature, i.e., they start recovering after detecting already occurred faults instead of preparing for possible future faults in a pre-emptive manner. The detection delays are especially problematic with regard to the zero latency requirements of 5G networks. To address this problem, existing SONs need to be upgraded from reactive to proactive response. One of the dimensions in SH research is to employ more…
Molecular Iodine for a General Synthesis of Binary and Ternary Inorganic and Hybrid Organic-inorganic Iodide Nanocrystals
We report the synthesis of various binary and ternary inorganic and hybrid organic–inorganic iodide nanocrystals (NCs) starting from molecular iodine (I2). The synthesis described herein utilizes a reaction between I2 and oleylamine, which results in oleylammonium iodide, an iodide precursor that can be directly used in the preparation of iodide-based NCs. The generality of the synthesis was demonstrated by synthesizing KI, RbI, CsI, AgI, CsPbI3, FAPbI3, Cs4PbI6, Cs3Bi2I9, FA3Bi2I9, and RbAg4I5 NCs. Furthermore, the syntheses are facile and are carried out in vials heated on a hot plate in air. They exhibit not only narrow size distributions, but also, in the case of lead-based perovskites …