0000000000299593
AUTHOR
Ziqi Hu
Electrical two-qubit gates within a pair of clock-qubit magnetic molecules
Enhanced coherence in HoW$_{10}$ molecular spin qubits has been demonstrated by use of Clock Transitions (CTs). More recently it was shown that, while operating at the CTs, it was possible to use an electrical field to selectively address HoW$_{10}$ molecules pointing in a given direction, within a crystal that contains two kinds of identical but inversion-related molecules. Herein we theoretically explore the possibility of employing the electric field to effect entangling two-qubit quantum gates among two neighbouring CT-protected HoW$_{10}$ qubits within a diluted crystal. We estimate the thermal evolution of $T_1$, $T_2$, find that CTs are also optimal operating points from the point of…
Near Isotropic D4d Spin Qubits as Nodes of a Gd(III)-Based Metal-Organic Framework
Embedding coherent spin motifs in reproducible molecular building blocks is a promising pathway for the realization of quantum technologies. Three-dimensional (3D) MOFs are a versatile platform for the rational design of extended structures employing coordination chemistry. Here, we report the synthesis and characterization of a gadolinium(III)-based MOF, [Gd(bipyNO)4](TfO)3·xMeOH (bipyNO = bipyridine,N,N′-dioxide; TfO = triflate; and MeOH = methanol) (quMOF-1), which presents a unique coordination geometry that leads to a tiny magnetic anisotropy (in terms of D, an equivalent zero-field splitting would be achieved by D = 0.006 cm–1) even compared with regular Gd(III) complexes. Pulsed elec…
Lanthanide molecular nanomagnets as probabilistic bits
Abstract Over the decades, the spin dynamics of a large set of lanthanide complexes have been explored. Lanthanide-based molecular nanomagnets are bistable spin systems, generally conceptualized as classical bits, but many lanthanide complexes have also been presented as candidate quantum bits (qubits). Here we offer a third alternative and model them as probabilistic bits (p-bits), where their stochastic behavior constitutes a computational resource instead of a limitation. We present a modelling tool for molecular spin p-bits, we demonstrate its capability to simulate bulk magnetic relaxation data and ac experiments and to simulate a minimal p-bit network under realistic conditions. Final…
Tunable luminescent lead bromide complexes
Lead halides are used extensively to prepare perovskite-based devices but it is less known that lead halides can also form luminescent complexes in solvents. Using polyethylene glycol as a solvent, a lead bromide complex with a photoluminescence quantum yield over 20% is obtained and the photoluminescence peak can be shifted around 50 nm with different alkylammonium bromides.
Binding Sites, Vibrations and Spin-Lattice Relaxation Times in Europium(II)-Based Metallofullerene Spin Qubits.
Abstract To design molecular spin qubits with enhanced quantum coherence, a control of the coupling between the local vibrations and the spin states is crucial, which could be realized in principle by engineering molecular structures via coordination chemistry. To this end, understanding the underlying structural factors that govern the spin relaxation is a central topic. Here, we report the investigation of the spin dynamics in a series of chemically designed europium(II)‐based endohedral metallofullerenes (EMFs). By introducing a unique structural difference, i. e. metal‐cage binding site, while keeping other molecular parameters constant between different complexes, these manifest the ke…