0000000000302319

AUTHOR

B. Bohn

showing 2 related works from this author

A comparison of HONO budgets for two measurement heights at a field station within the boreal forest in Finland

2015

Atmospheric concentrations of nitrous acid (HONO), one of the major precursors of the hydroxyl radical (OH) in the troposphere, significantly exceed the values predicted by the assumption of a photostationary state (PSS) during daytime. Therefore, additional sources of HONO were intensively investigated in the last decades. This study presents budget calculations of HONO based on simultaneous measurements of all relevant species, including HONO and OH at two different measurement heights, i.e. 1 m above the ground and about 2 to 3 m above the canopy (24 m above the ground), conducted in a boreal forest environment. We observed mean HONO concentrations of about 6.5 × 108 molecules cm−3 (26 p…

Meteorologie en Luchtkwaliteit1171 Geosciences4112 ForestryPHOTOLYSIS FREQUENCYMeteorology and Air Qualityeducation116 Chemical sciencesBOUNDARY-LAYERSURFACE-ADSORBED HNO3HETEROGENEOUS HYDROLYSISGAS-PHASE114 Physical scienceslcsh:QC1-999lcsh:ChemistryRING-DOWN SPECTROSCOPYNITRIC-ACIDVERTICAL GRADIENTSlcsh:QD1-999ddc:550Life ScienceNITROUS-ACID HONOATMOSPHERIC CHEMISTRY1172 Environmental scienceslcsh:Physics
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Daytime formation of nitrous acid at a coastal remote site in Cyprus indicating a common ground source of atmospheric HONO and NO

2016

Characterization of daytime sources of nitrous acid (HONO) is crucial to understand atmospheric oxidation and radical cycling in the planetary boundary layer. HONO and numerous other atmospheric trace constituents were measured on the Mediterranean island of Cyprus during the CYPHEX (CYprus PHotochemical EXperiment) campaign in summer 2014. Average volume mixing ratios of HONO were 35 pptv (±25 pptv) with a HONO ∕ NOx ratio of 0.33, which was considerably higher than reported for most other rural and urban regions. Diel profiles of HONO showed peak values in the late morning (60 ± 28 pptv around 09:00 local time) and persistently high mixing ratios during daytime (45 ± 18 pptv), indicating …

lcsh:Chemistrylcsh:QD1-999lcsh:Physicslcsh:QC1-999Atmospheric Chemistry and Physics
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