Electrochemical Treatment of Synthetic Wastewaters Contaminated by Organic Pollutants at Ti 4 O 7 Anode. Study of the Role of Operative Parameters by…

2022

In the last years, an increasing attention has been devoted to the utilization of anodic oxidation (AO) technologies for the treatment of wastewater polluted by recalcitrant organics. Recently, Ti4O7 was proposed as a promising anode for AO for the treatment of various organics. Here the potential utilization of commercial Ti4O7 anodes has been evaluated considering the electrochemical treatment of synthetic wastewater contaminated by three very different organic molecules (namely, oxalic acid, phenol and Acid Orange 7), all characterized by a very high resistance to AO. The performances of Ti4O7 were compared with that of two largely investigated anodes: Boron-doped diamond (BDD), which is…

Removal of Phenol from Water in the Presence of NaCl in Undivided Cells Equipped with Carbon Felt or Ni Cathodes: Effect of Air Pressure

2022

Recently, the electrochemical treatment of wastewater polluted by recalcitrant organics and containing chlorides was shown to be significantly improved adopting proper operative conditions such as suitable anodes and cathodes and low current density. In particular, the use of suitable cathodes such as carbon felt or silver could increase the removal of TOC and reduce the formation of chlorinated by-products. In this study, attention was focused on the utilization of carbon felt cathodes with the main aim to evaluate the effect of air pressure on the process using phenol as model organic pollutant. It was shown that, in the presence of carbon felt cathode, the use of pressurized air allows b…

Electrochemical treatment of wastewater contaminated by organics and containing chlorides: Effect of operative parameters on the abatement of organic…

2022

Abstract In the last years, large attention has been devoted to the electrochemical treatment of wastewater polluted by recalcitrant organics and containing chlorides. However, the utilization on an applicative scale of this route is limited by the fact that usually it is not possible to achieve high removals of organics without the generation of significant amounts of chlorinated by-products. Here, the role of several operative parameters on the performances of the process was systematically evaluated using phenol as a model organic pollutant. It was shown that the removal of phenol and TOC and the generation of many by-products including chlorophenols, chloroacetic acids, chlorate and per…

Electrochemical treatment of wastewater containing NaCl. Methods to increase the removal of organic pollutants and minimize the formation of toxic by…

In many cases, wastewater can contain both organic pollutants and NaCl. Electrochemical methods allow to treat very effectively organic pollutants in the presence of NaCl. However, the utilization on an applicative scale of this route is limited by the fact that usually the high removals of organics is coupled with the generation of significant amounts of chlorinated by-products. The role of several operative parameters on the performances of the process was systematically evaluated using phenol as a model organic pollutant. It was shown that the removal of phenol and TOC and the generation of many by-products including chlorophenols, chloroacetic acids, chlorate and perchlorate dramaticall…