0000000000305581
AUTHOR
Hongrui Ma
Electrochemical Treatment of Synthetic Wastewaters Contaminated by Organic Pollutants at Ti 4 O 7 Anode. Study of the Role of Operative Parameters by Experimental Results and Theoretical Modelling
In the last years, an increasing attention has been devoted to the utilization of anodic oxidation (AO) technologies for the treatment of wastewater polluted by recalcitrant organics. Recently, Ti4O7 was proposed as a promising anode for AO for the treatment of various organics. Here the potential utilization of commercial Ti4O7 anodes has been evaluated considering the electrochemical treatment of synthetic wastewater contaminated by three very different organic molecules (namely, oxalic acid, phenol and Acid Orange 7), all characterized by a very high resistance to AO. The performances of Ti4O7 were compared with that of two largely investigated anodes: Boron-doped diamond (BDD), which is…
Removal of Phenol from Water in the Presence of NaCl in Undivided Cells Equipped with Carbon Felt or Ni Cathodes: Effect of Air Pressure
Recently, the electrochemical treatment of wastewater polluted by recalcitrant organics and containing chlorides was shown to be significantly improved adopting proper operative conditions such as suitable anodes and cathodes and low current density. In particular, the use of suitable cathodes such as carbon felt or silver could increase the removal of TOC and reduce the formation of chlorinated by-products. In this study, attention was focused on the utilization of carbon felt cathodes with the main aim to evaluate the effect of air pressure on the process using phenol as model organic pollutant. It was shown that, in the presence of carbon felt cathode, the use of pressurized air allows b…
Reduction of oxygen to H2O2 at carbon felt cathode in undivided cells. Effect of the ratio between the anode and the cathode surfaces and of other operative parameters
Abstract In the last years, the electrochemical conversion of oxygen to hydrogen peroxide at carbon felt has been largely studied in order to define a new route for the production of H2O2 and to optimize the electro-Fenton process, which is based on the cathodic generation of H2O2. In particular, many studies regarding electro-Fenton process were carried out in undivided cells in order to avoid the costs of the separator and to reduce the cell potentials. Hence, in order to optimize the cathodic conversion of oxygen to H2O2 in undivided cells, the effect of many parameters linked to the anodic process were here evaluated. In particular, it was demonstrated that the performances of the proce…
Electrochemical treatment of wastewater contaminated by organics and containing chlorides: Effect of operative parameters on the abatement of organics and the generation of chlorinated by-products
Abstract In the last years, large attention has been devoted to the electrochemical treatment of wastewater polluted by recalcitrant organics and containing chlorides. However, the utilization on an applicative scale of this route is limited by the fact that usually it is not possible to achieve high removals of organics without the generation of significant amounts of chlorinated by-products. Here, the role of several operative parameters on the performances of the process was systematically evaluated using phenol as a model organic pollutant. It was shown that the removal of phenol and TOC and the generation of many by-products including chlorophenols, chloroacetic acids, chlorate and per…
Electrochemical treatment of real wastewater. Part 1: Effluents with low conductivity
Abstract The treatment of a real wastewater characterized by low conductivity was performed by anodic oxidation at boron doped diamond (BDD) in both conventional and microfluidic cells. The electrolyses carried out in conventional cells without supporting electrolyte were characterized by very high TOC removals but excessively high energetic consumptions and operating costs. The addition of sodium sulphate, as supporting electrolyte, allowed to strongly reduce the cell potentials and consequently the energetic consumptions and the operating costs. However, under various operating conditions, the addition of Na2SO4 caused a lower removal of the TOC. The best results in terms of both TOC remo…