Halogen diffusion in a basaltic melt

Abstract The diffusion of the halogens fluorine, chlorine and bromine was measured in a hawaiitic melt from Mt. Etna at 500 MPa and 1.0 GPa, 1250 to 1450 °C at anhydrous conditions; the diffusion of F and Cl in the melt was also studied with about 3 wt% of dissolved water. Experiments were performed using the diffusion-couple technique in a piston cylinder. Most experiments were performed with only one halogen diffusing between the halogen-enriched and halogen-poor halves of the diffusion couple, but a few experiments with a mixture of halogens (F, Cl and Br) were also performed in order to investigate the possibility of interactions between the halogens during diffusion. Fluorine and chlor…

Fluid/melt partitioning coefficients of chlorine in basaltic melt

Fluid/Melt Partition Coefficients Of Halogens In Basaltic Melt

Chlorine Partitioning Between a Basaltic Melt and H2O-CO2 Fluids at Mount Etna

Partitioning experiments between a basaltic melt from Mt. Etna and a low-density hydrous fluid or vapor containing H(2)O or H(2)O-CO(2) were performed at 1200-1260 degrees C, at pressures between 1 and 200 MPa, either near the nickel-nickel oxide (NNO) buffer or at two log units above it (NNO + 2), and with different chloride concentrations. Most of the experiments were done at chloride-brine-undersaturated conditions, although at the highest Cl concentrations explored brine saturation might have been reached. The average partition coefficients (D(Cl)(fluid/melt)) over the range of Cl concentrations were derived on a weight basis by plotting the calculated concentrations of Cl in the fluid …

Mafic and ultra-mafic enclaves from Ustica island lava: inferences on deep magmatic processes

Ustica Island, southern Tyrrhenian Sea, is constituted of Quaternary alkaline volcanics. Avariety of enclaves representative of deep to supra-crustal settings were recently found in a hawaiitic lava flow. Enclaves consist of: (i) Ultramafic meta-cumulates, i.e. clinopyroxenites and wherlites characterized by variably deformed porphyroclastic to granoblastic textures. (ii) Mafic cumulates, i.e. gabbros (F amphibole) and troctolites, the first often characterized by frequent amphibole breakdown coronas (olivine+Tiaugite+ plagioclase+magnetite+ilmenite+rhfnite) in response to an H2O decrease during the ascent, while the troctolites interpreted as meta-cumulates. (iii) Microsyenites, consist of…

Petrology of enclaves from Ustica Island (Italy): insights on time scale of magma ascent