0000000000312147
AUTHOR
Luis Morales
Potential ATPase mimics by polyammonium macrocycles: Criteria for catalytic activity
Abstract A series of polyammonium macrocycles, ranging in size from the 18-membered ring [18]aneN6 to the 36-membered [36]aneN12 were examined as potential ATPase mimics. The rates of hydrolysis of ATP were followed at pH 3.0 and 7.0 using 31P NMR and HPLC techniques. Stability constants as a function of degree of protonation, distribution curves for the ligands as a function of pH, and distribution curves for the mixed species of nucleotides, inorganic phosphate, and macrocycle were also determined. All of the macrocycles catalyzed the hydrolysis of ATP to some extent compared to noncatalyzed hydrolysis. A critical dependence on macrocyclic ring size was observed, with [21]aneN7 being the …
Trends in column integrated water vapour over Europe from 1973 to 2003
The spatial and temporal variations of atmospheric precipitable water (PW) content anomalies were analysed over Europe from 1973 to 2003 using daily data (0000 and 1200 UTC) from National Center of Environmental Prediction and National Center of Atmospheric Research Reanalysis project (NCEP-1) and in situ radiosonde data. Mann–Kendall trend tests were applied to long-term PW time series. Technology changes influence PW radiosonde trends, although these are in agreement with NCEP-1 trends. Over the south of the Iberian Peninsula, trends are negative and statistically significant ( 0.04 mm year−1; p < 0.05). Seasonal trends revealed negative and significant trends over the Iberian Peninsula f…
Thermal remote sensing from Airborne Hyperspectral Scanner data in the framework of the SPARC and SEN2FLEX projects: an overview
Abstract. The AHS (Airborne Hyperspectral Scanner) instrument has 80 spectral bands covering the visible and near infrared (VNIR), short wave infrared (SWIR), mid infrared (MIR) and thermal infrared (TIR) spectral range. The instrument is operated by Instituto Nacional de Técnica Aerospacial (INTA), and it has been involved in several field campaigns since 2004. This paper presents an overview of the work performed with the AHS thermal imagery provided in the framework of the SPARC and SEN2FLEX campaigns, carried out respectively in 2004 and 2005 over an agricultural area in Spain. The data collected in both campaigns allowed for the first time the development and testing of algorithms for …
Thermal remote sensing in the framework of the SEN2FLEX project: field measurements, airborne data and applications
A description of thermal radiometric field measurements carried out in the framework of the European project SENtinel-2 and Fluorescence Experiment (SEN2FLEX) is presented. The field campaign was developed in the region of Barrax (Spain) during June and July 2005. The purpose of the thermal measurements was to retrieve biogeophysical parameters such as land surface emissivity (LSE) and temperature (LST) to validate airborne-based methodologies and to characterize different surfaces. Thermal measurements were carried out using two multiband field radiometers and several broadband field radiometers, pointing at different targets. High-resolution images acquired with the Airborne Hyperspectral…
Multitemporal analysis of PAL images for the study of land cover dynamics in South America
Pathfinder AVHHR Land (PAL) database has been used for the retrieval of Land Surface Temperature (LST) over South America, which, along with NDVI parameter, will allow the studying of the evolution of the vegetation between July 1981 and September 2001. To this end, a classification has been built, based on PAL NDVI and Reanalysis air temperature at 2 m height data. This classification takes into account both vegetation and thermal patterns, and has been validated by a comparison with CAZALAC's map of arid zones (Centro del Agua para Zonas Aridas y semiaridas de Latino-America y el Caribe), as well as with Global Land Cover Characteristics' classification built by the USGS (United States Ge…
Changes in vegetation spring dates in the second half of the twentieth century
This study aims at estimating trends in spring phenology from vegetation index and air temperature at 2 m height. To this end, we have developed a methodology to infer spring phenological dates from Global Inventory Modeling and Mapping Studies GIMMS Normalized Difference Vegetation Index NDVI time-series, which are then extrapolated to the period 1948–2006 with the help of Reanalysis data, using its 2 m height air temperature parameter. First, yearly NDVI is fitted to a double-logistic function for the whole extent of the GIMMS database 1981–2003. This fitting procedure allows us to describe, on a yearly basis, the NDVI evolution for each pixel through the estimation of six parameters whic…
Estimación de la temperatura superficial del mar desde datos satelitales NOAA-AVHRR: validación de algoritmos aplicados a la costa norte de Chile
Se aplicaron y compararon tres algoritmos del tipo Split-Window (SW), que permitieron estimar la temperatura superficial del mar desde datos aportados por el sensor Advanced Very High Resolution Radiometer (AVHRR), a bordo de la serie de satélites de la National Oceanic and Atmospheric Administration (NOAA). La validación de los algoritmos fue lograda por comparación con mediciones in situ de temperatura del mar provenientes de una boya hidrográfica, ubicada frente a la costa norte de Chile (21°21'S, 70°6'W; Región de Tarapacá), a 3 km de la costa aproximadamente. Los mejores resultados se obtuvieron por aplicación del algoritmo propuesto por Sobrino & Raissouni (2000). En efecto, diferenci…
Application of a Split-Window Algorithm to Estimate Land Surface Temperature from NOAA-AVHRR Data
Estimaciones de temperatura de la superficie terrestre, en días parciales a completamente despejados, fueron realizadas a partir de los datos proporcionados por el sensor Advanced Very High Resolution Radiometer (AVHRR), a bordo de la serie de satélites de la National Oceanic and Atmospheric Administration (NOAA) por aplicación de un algoritmo basado en el método de Split-Window. El algoritmo utilizado supone correcciones por emisividad y contenido de vapor de agua atmosférico, y fue validado con mediciones de temperatura de la superficie terrestre realizadas en terreno. Para esto, un data logger LI-1000 se instaló en la Estación Agrometeorológica dependiente del Instituto de Investigacione…