Ultrastrong Coupling of a Single Molecule to a Plasmonic Nanocavity: A First-Principles Study
| openaire: EC/H2020/838996/EU//RealNanoPlasmon Funding Information: We acknowledge financial support from the Swedish Research Council (VR Miljö, Grant No: 2016-06059), the Knut and Alice Wallenberg Foundation (Grant No: 2019.0140), the Polish National Science Center (projects 2019/34/E/ST3/00359 and 2019/35/B/ST5/02477). T.P.R. acknowledges support from the European Union’s Horizon 2020 research and innovation program under the Marie Skłodowska-Curie Grant Agreement No. 838996 and support from the Academy of Finland under the Grant No. 332429. T.J.A. acknowledges support from the Project HPC-EUROPA3 (INFRAIA-2016-1-730897), with the support of the EC Research Innovation Action under the H…
Dipolar coupling of nanoparticle-molecule assemblies: An efficient approach for studying strong coupling
Strong light-matter interactions facilitate not only emerging applications in quantum and non-linear optics but also modifications of materials properties. In particular the latter possibility has spurred the development of advanced theoretical techniques that can accurately capture both quantum optical and quantum chemical degrees of freedom. These methods are, however, computationally very demanding, which limits their application range. Here, we demonstrate that the optical spectra of nanoparticle-molecule assemblies, including strong coupling effects, can be predicted with good accuracy using a subsystem approach, in which the response functions of the different units are coupled only a…