0000000000319772

AUTHOR

Gabriele Di Carlo

0000-0002-8782-7945

showing 7 related works from this author

New Internal-Charge-Transfer Second-Order Nonlinear Optical Chromophores Based on the Donor Ferrocenylpyrazole Moiety

2016

A series of new N-arylated ferrocenepyrazole structures, carrying different donor or acceptor substituents in the para position of the aryl ring, has been synthesized by the Chan-Lam cross-coupling reaction. The nonplanar geometric molecular structure of some of these chromophores together with their crystal packing was determined by X-ray diffraction, and the HOMO and LUMO energy levels were evaluated by electrochemical and optical measurements and by density functional theoretical (DFT) calculations. By the investigation of solvent effects and time-dependent DFT (TD-DFT) calculations, the intense electronic absorption band around 270-310 nm was confirmed to be an internal-chargetransfer (…

Hyperpolarizability010402 general chemistryPhotochemistry01 natural scienceschemistry.chemical_compoundnonlinear optical responsearylationPhysical and Theoretical ChemistryHOMO/LUMOta116010405 organic chemistryArylN-arylated ferrocenepyrazole; internal-charge-transfer; NLO; DDA chromophoreSecond-harmonic generationChromophoreAcceptor0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyGeneral EnergychemistryAbsorption bandSolvent effectsferrocenepyrazoleelectronic absorptionJournal of Physical Chemistry C
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Evaluation of the orthodontic treatment need in a paediatric sample from Southern Italy and its importance among paediatricians for improving oral he…

2017

Background Data from epidemiological studies investigating the prevalence and severity of malocclusions in children are of great relevance to public health programs aimed at orthodontic prevention. Previous epidemiological studies focused mainly on the adolescence age group and reported a prevalence of malocclusion with a high variability, going from 32% to 93%. Aim of our study was to assess the need for orthodontic treatment in a paediatric sample from Southern Italy in order to improve awareness among paediatricians about oral health preventive strategies in pediatric dentistry. Material and methods The study used the IOTN-DHC index to evaluate the need for orthodontic treatment for seve…

medicine.medical_specialtyOverjetMEDLINEDentistrySample (statistics)Overbite03 medical and health sciences0302 clinical medicineEpidemiologymedicine030212 general & internal medicineGeneral DentistryOrthodonticsdentistry (all)Crossbitebusiness.industryPublic healthResearchmalocclusion030206 dentistry:CIENCIAS MÉDICAS [UNESCO]medicine.diseasepediatric dentistryCommunity and Preventive DentistryUNESCO::CIENCIAS MÉDICASoral healthorthodontic treatmentMalocclusionbusinessmalocclusion; oral health; orthodontic treatment; pediatric dentistry; dentistry (all)Journal of Clinical and Experimental Dentistry
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Prevalence of maxillary canine impaction in skeletal Class III malocclusions compared to Class I malocclusions

2019

Background The aim of the present investigation was to evaluate if an orthodontic population of Class III malocclusion patients shows a different prevalence of maxillary canine impaction than Class I subjects. Material and methods Fifty-eight subjects were retrospectively selected and assigned to the Class I group (n= 32) or the Class III group (n= 26), depending on the ANB and WITS values. Lateral cephalograms were used to collect angular and linear measurements that described the skeletal and dental maxillary features of the subjects, while orthopantomography was used to assess the impaction or the correct eruption of the maxillary canines. An independent samples T-test or a Mann-Whitney …

Populationtooth impactionOrthodontics03 medical and health sciences0302 clinical medicineangle Class IIImaxillary canine impactionTooth impactionMedicine030212 general & internal medicineeducationskeletal Class IIIGeneral DentistryOrthodonticseducation.field_of_studybusiness.industryClass iii malocclusionImpactionResearchSignificant differenceMaxillary canineskeletal Class III; angle Class III; maxillary canine impaction; tooth impaction030206 dentistrymedicine.diseaseSkeletal class:CIENCIAS MÉDICAS [UNESCO]UNESCO::CIENCIAS MÉDICASbusinessAngle class iii
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CCDC 1428469: Experimental Crystal Structure Determination

2016

Related Article: Kabali Senthilkumar, Maddalena Pizzotti, Krishnan Thirumoorthy, Gabriele Di Carlo, Stefania Righetto, Alessio Orbelli Biroli, Matti Haukka, Nallasamy Palanisami|2016|J.Phys.Chem.C|120|20277|doi:10.1021/acs.jpcc.6b06364

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates1-(4-nitrophenyl)-5-methyl-3-ferrocenyl-1H-pyrazole
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CCDC 1421537: Experimental Crystal Structure Determination

2016

Related Article: Kabali Senthilkumar, Maddalena Pizzotti, Krishnan Thirumoorthy, Gabriele Di Carlo, Stefania Righetto, Alessio Orbelli Biroli, Matti Haukka, Nallasamy Palanisami|2016|J.Phys.Chem.C|120|20277|doi:10.1021/acs.jpcc.6b06364

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters3-ferrocenyl-1-(4-fluorophenyl)-5-methyl-1H-pyrazoleExperimental 3D Coordinates
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CCDC 1421536: Experimental Crystal Structure Determination

2016

Related Article: Kabali Senthilkumar, Maddalena Pizzotti, Krishnan Thirumoorthy, Gabriele Di Carlo, Stefania Righetto, Alessio Orbelli Biroli, Matti Haukka, Nallasamy Palanisami|2016|J.Phys.Chem.C|120|20277|doi:10.1021/acs.jpcc.6b06364

Space GroupCrystallographyCrystal System4-(3-ferrocenyl-5-methyl-1H-pyrazol-1-yl)benzaldehydeCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421538: Experimental Crystal Structure Determination

2016

Related Article: Kabali Senthilkumar, Maddalena Pizzotti, Krishnan Thirumoorthy, Gabriele Di Carlo, Stefania Righetto, Alessio Orbelli Biroli, Matti Haukka, Nallasamy Palanisami|2016|J.Phys.Chem.C|120|20277|doi:10.1021/acs.jpcc.6b06364

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-(3-ferrocenyl-5-methyl-1H-pyrazol-1-yl)benzonitrileExperimental 3D Coordinates
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