0000000000323900
AUTHOR
Frank W. Heinemann
A non-heme dinuclear iron(II) complex containing a single, unsupported hydroxo bridge.
Complexation of the tetrapodal pentadentate NN4 ligand 2,6-C5H3N[CMe(CH2NH2)2]2 (I) with iron(II) perchlorate hydrate in methanol, in the presence of N-methylimidazole, produces a diferrous complex with a single, unsupported mu-OH ligand between two {(I)FeII} coordination modules.
Syntheses, Characterization, and Magnetic Studies of Copper(II) Complexes with the Ligand N,N,N′,N′-Tetrakis(2-pyridylmethyl)-1,3-benzenediamine (1,3-tpbd) and its Phenol Derivative 2,6-Bis[bis(2-pyridylmethyl)amino]-p-cresol] (2,6-Htpcd)
The copper(II) complexes [Cu4(1,3-tpbd)2(H2O)4(NO3)4]n(NO3)4n·13nH2O (1), [Cu4(1,3-tpbd)2(AsO4)(ClO4)3(H2O)](ClO4)2·2H2O·0.5CH3OH (2), [Cu4(1,3-tpbd)2(PO4)(ClO4)3(H2O)](ClO4)2·2H2O·0.5CH3OH (3), [C...