6533b7d8fe1ef96bd126ad38
RESEARCH PRODUCT
A non-heme dinuclear iron(II) complex containing a single, unsupported hydroxo bridge.
Matthias GrunertHolger KämpfJesús Pitarch LópezFrank W. HeinemannRaju PrakashPhilipp GütlichAndreas Grohmannsubject
LigandStereochemistryMetals and AlloysGeneral ChemistryBridge (interpersonal)CatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsPerchloratechemistry.chemical_compoundCrystallographychemistryMaterials ChemistryCeramics and CompositesNon hemeMethanolHydratedescription
Complexation of the tetrapodal pentadentate NN4 ligand 2,6-C5H3N[CMe(CH2NH2)2]2 (I) with iron(II) perchlorate hydrate in methanol, in the presence of N-methylimidazole, produces a diferrous complex with a single, unsupported mu-OH ligand between two {(I)FeII} coordination modules.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2006-04-13 | Chemical communications (Cambridge, England) |