Author: Hengbo Cui

0000000000329427

AUTHOR

Hengbo Cui

showing 6 related works from this author

Magnetic Molecular Conductors Based on Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) and the Tris(chlorocyananilato)ferrate(III) Complex

2019

Electrocrystallization of the bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) organic donor in the presence of the [Fe(ClCNAn)3]3– tris(chlorocyananilato)ferrate(III) paramagnetic anion in different stoichiometric ratios and solvent mixtures afforded two different hybrid systems formulated as [BEDT-TTF]4[Fe(ClCNAn)3]·3H2O (1) and [BEDT-TTF]5[Fe(ClCNAn)3]2·2CH3CN (2) (An = anilato). Compounds 1 and 2 present unusual structures without the typical segregated organic and inorganic layers, where layers of 1 are formed by Λ and Δ enantiomers of the anionic paramagnetic complex together with mixed-valence BEDT-TTF tetramers, while layers of 2 are formed by Λ and Δ enantiomers of the paramagnetic…

Crystal structure010402 general chemistry01 natural sciencesInorganic Chemistrychemistry.chemical_compoundParamagnetismMolecular interactionsMolecule[CHIM.COOR]Chemical Sciences/Coordination chemistryPhysical and Theoretical Chemistry010405 organic chemistry[CHIM.MATE]Chemical Sciences/Material chemistryMolecules3. Good health0104 chemical sciencesSolventCrystallographyMonomerchemistryRadical ionOligomersCrystal structuresSolventsStoichiometryTetrathiafulvaleneInorganic Chemistry

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Role of the Open-Shell Character on the Pressure-Induced Conductivity of an Organic Donor-Acceptor Radical Dyad

2018

Single‐component conductors based on neutral organic radicals have received a lot of attention due to the possibility that the unpaired electron can serve as a charge carrier without the need of a previous doping process. Although most of these systems are based on delocalized planar radicals, we present here a nonplanar and spin localized radical based on a tetrathiafulvalene (TTF) moiety, linked to a perchlorotriphenylmethyl (PTM) radical by a conjugated bridge, which exhibits a semiconducting behavior upon application of high pressure. The synthesis, electronic properties, and crystal structure of this neutral radical TTF‐Ph‐PTM derivative (1) are reported and implications of its crystal…

010405 organic chemistryChemistryRadicalOrganic ChemistryGeneral ChemistryOrganic radical010402 general chemistry01 natural sciencesCatalysisDonor-acceptor3. Good health0104 chemical sciencesSingle-component conductorDelocalized electronchemistry.chemical_compoundCrystallographyUnpaired electronTetrathiafulvaleneCharge carrierIsostructuralElectronic band structureOpen shellPolychlorotriphenylmethylTetrathiafulvaleneChemistry - A European Journal

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CCDC 1817871: Experimental Crystal Structure Determination

2018

Related Article: Manuel Souto, Maria Chiara Gullo, HengBo Cui, Nicola Casati, Fabio Montisci, Harald O. Jeschke, Roser Valentí, Imma Ratera, Concepció Rovira, Jaume Veciana|2018|Chem.-Eur.J.|24|5500|doi:10.1002/chem.201800881

Space GroupCrystallography4-[4-(2-{4-[bis(pentachlorophenyl)methyl]-2356-tetrachlorophenyl}ethenyl)phenyl]-2-(2H-13-dithiol-2-ylidene)-2H-13-dithioleCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

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CCDC 1817872: Experimental Crystal Structure Determination

2018

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-[4-(2-{4-[bis(pentachlorophenyl)methyl]-2356-tetrachlorophenyl}ethenyl)phenyl]-2-(2H-13-dithiol-2-ylidene)-2H-13-dithiole radicalExperimental 3D Coordinates

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CCDC 1945945: Experimental Crystal Structure Determination

2019

Related Article: Suchithra Ashoka Sahadevan, Alexandre Abhervé, Noemi Monni, Pascale Auban-Senzier, Joan Cano, Francesc Lloret, Miguel Julve, Hengbo Cui, Reizo Kato, Enric Canadell, Maria Laura Mercuri, Narcis Avarvari|2019|Inorg.Chem.|58|15359|doi:10.1021/acs.inorgchem.9b02404

pentakis(bis(ethylenedithio)tetrathiafulvalene radical) bis(tris(chlorocyananilato)-iron(iii)) acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

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CCDC 1945944: Experimental Crystal Structure Determination

2019

Space GroupCrystallographytetrakis(bis(ethylenedithio)tetrathiafulvalene radical) tris(chlorocyananilato)-iron(iii) trihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

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