0000000000329428

AUTHOR

Reizo Kato

showing 3 related works from this author

Magnetic Molecular Conductors Based on Bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) and the Tris(chlorocyananilato)ferrate(III) Complex

2019

Electrocrystallization of the bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) organic donor in the presence of the [Fe(ClCNAn)3]3– tris(chlorocyananilato)ferrate(III) paramagnetic anion in different stoichiometric ratios and solvent mixtures afforded two different hybrid systems formulated as [BEDT-TTF]4[Fe(ClCNAn)3]·3H2O (1) and [BEDT-TTF]5[Fe(ClCNAn)3]2·2CH3CN (2) (An = anilato). Compounds 1 and 2 present unusual structures without the typical segregated organic and inorganic layers, where layers of 1 are formed by Λ and Δ enantiomers of the anionic paramagnetic complex together with mixed-valence BEDT-TTF tetramers, while layers of 2 are formed by Λ and Δ enantiomers of the paramagnetic…

Crystal structure010402 general chemistry01 natural sciencesInorganic Chemistrychemistry.chemical_compoundParamagnetismMolecular interactionsMolecule[CHIM.COOR]Chemical Sciences/Coordination chemistryPhysical and Theoretical Chemistry010405 organic chemistry[CHIM.MATE]Chemical Sciences/Material chemistryMolecules3. Good health0104 chemical sciencesSolventCrystallographyMonomerchemistryRadical ionOligomersCrystal structuresSolventsStoichiometryTetrathiafulvaleneInorganic Chemistry
researchProduct

CCDC 1945945: Experimental Crystal Structure Determination

2019

Related Article: Suchithra Ashoka Sahadevan, Alexandre Abhervé, Noemi Monni, Pascale Auban-Senzier, Joan Cano, Francesc Lloret, Miguel Julve, Hengbo Cui, Reizo Kato, Enric Canadell, Maria Laura Mercuri, Narcis Avarvari|2019|Inorg.Chem.|58|15359|doi:10.1021/acs.inorgchem.9b02404

pentakis(bis(ethylenedithio)tetrathiafulvalene radical) bis(tris(chlorocyananilato)-iron(iii)) acetonitrile solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1945944: Experimental Crystal Structure Determination

2019

Related Article: Suchithra Ashoka Sahadevan, Alexandre Abhervé, Noemi Monni, Pascale Auban-Senzier, Joan Cano, Francesc Lloret, Miguel Julve, Hengbo Cui, Reizo Kato, Enric Canadell, Maria Laura Mercuri, Narcis Avarvari|2019|Inorg.Chem.|58|15359|doi:10.1021/acs.inorgchem.9b02404

Space GroupCrystallographytetrakis(bis(ethylenedithio)tetrathiafulvalene radical) tris(chlorocyananilato)-iron(iii) trihydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct