0000000000331945
AUTHOR
Carolin Regenbrecht
showing 3 related works from this author
Highly selective generation of vanillin by anodic degradation of lignin: a combined approach of electrochemistry and product isolation by adsorption
2015
The oxidative degradation of lignin into a variety of valuable products has been under investigation since the first half of the last century. Especially, the chance to claim this cheap, abundant and renewable source for the production of the important aroma chemical vanillin (1) was one of the major driving forces of lignin research. So far most of the developed methods fail in technical application since no viable concept for work-up is included. This work represents a combined approach of electrochemical conversion of Kraft lignin and product recovery by adsorption on a strongly basic anion exchange resin. Electrolysis conditions are optimized regarding reaction temperatures below 100 °C…
Adsorption and separation of black liquor-derived phenol derivatives using anion exchange resins
2017
Abstract Kraft black liquor is the major waste stream of the paper pulping industry. This stream is usually directly incinerated in such facilities for energy production and recycling of the inorganic chemicals involved. However, lignin and other low molecular organic fragments dissolved in black liquor give rise to a large variety of aromatic fine chemicals. Energetic use of black liquor and its components prevents the removal of these valuable compounds from the waste stream. We present an easy protocol for adsorption and selective desorption of low molecular phenol derivatives from black liquor depending on the composition of the desorption system. Furthermore, adsorption experiments in …
Efficient electroorganic synthesis of 2,3,6,7,10,11-hexahydroxytriphenylene derivatives
2012
2,3,6,7,10,11-Hexahydroxytriphenylene of good quality and purity can be obtained via anodic treatment of catechol ketals and subsequent acidic hydrolysis. The electrolysis is conducted in propylene carbonate circumventing toxic and expensive acetonitrile. The protocol is simple to perform and superior to other chemical or electrochemical methods. The key of the method is based on the low solubility of the anodically trimerized product. The shift of potentials is supported by cyclic voltammetry studies.