0000000000333631

AUTHOR

Sadaf Hanif

showing 3 related works from this author

Block copolymers from ionic liquids for the preparation of thin carbonaceous shells

2017

This paper describes the controlled radical polymerization of an ionic-liquid monomer by RAFT polymerization. This allows the control over the molecular weight of ionic liquid blocks in the range of 8000 and 22000 and of the block-copolymer synthesis. In this work we focus on block copolymers with an anchor block. They can be used to control the formation of TiO2 nanoparticles, which are functionalized thereafter with a block of ionic-liquid polymer. Pyrolysis of these polymer functionalized inorganic nanoparticles leads to TiO2 nanoparticles coated with a thin carbonaceous shell. Such materials may, e.g., be interesting as battery materials.

polymeric ionic liquidRadical polymerizationblock copolymer02 engineering and technology010402 general chemistry01 natural sciencesFull Research Paperlcsh:QD241-441chemistry.chemical_compoundlcsh:Organic chemistryPolymer chemistryCopolymerReversible addition−fragmentation chain-transfer polymerizationlcsh:Scienceionic liquidchemistry.chemical_classificationRAFT polymerizationcarbonOrganic ChemistryPolymer021001 nanoscience & nanotechnologyBlock (periodic table)0104 chemical sciencesChemistryMonomerchemistryIonic liquidlcsh:Q0210 nano-technologyPyrolysisBeilstein Journal of Organic Chemistry
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Facile Synthesis of Fluorescent Polymer Nanoparticles by Covalent Modification-Nanoprecipitation of Amine-Reactive Ester Polymers

2015

Emission wavelength control in fluorescent nanoparticles (NPs) is crucial for their applications. In the case of inorganic quantum dots or dye-impregnated silica NPs, such a control is readily achieved by changing the size of the particles or choosing appropriate fluorescent dyes, respectively. A similar modular approach for controlling the emission wavelength of fluo-rescent polymer NPs, however, is difficult. This article reports on fluorescent polymer NPs, the synthesis of which provides a platform for a modular approach towards the preparation of fluorescent NPs of desired emission wavelength. Atom-transfer radical polymerization (ATRP) is employed to synthesize reactive ester polymers,…

inorganic chemicalschemistry.chemical_classificationMagnetic Resonance SpectroscopyMaterials sciencePolymers and PlasticsPolymersAtom-transfer radical-polymerizationOrganic ChemistryDispersityRadical polymerizationtechnology industry and agricultureNanoparticleQuantum yieldEstersPolymerrespiratory systemPhotochemistryFluorescencePolymerizationchemistryQuantum dotMaterials ChemistryNanoparticlesAminesFluorescent DyesMacromolecular Rapid Communications
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Geoeconomic variations in epidemiology, ventilation management, and outcomes in invasively ventilated intensive care unit patients without acute resp…

2022

Contains fulltext : 252214.pdf (Publisher’s version ) (Open Access) BACKGROUND: Geoeconomic variations in epidemiology, the practice of ventilation, and outcome in invasively ventilated intensive care unit (ICU) patients without acute respiratory distress syndrome (ARDS) remain unexplored. In this analysis we aim to address these gaps using individual patient data of four large observational studies. METHODS: In this pooled analysis we harmonised individual patient data from the ERICC, LUNG SAFE, PRoVENT, and PRoVENT-iMiC prospective observational studies, which were conducted from June, 2011, to December, 2018, in 534 ICUs in 54 countries. We used the 2016 World Bank classification to defi…

MaleSociodemographic FactorsRespiration Artificial/methodsARDS ; mechanical ventilationSeverity of Illness IndexNOSettore MED/41 - ANESTESIOLOGIA80 and overTidal VolumeHumansHospital MortalityProspective Studiesddc:610Developing CountriesAgedHospital Mortality/trendsAged 80 and overDeveloped Countries/statistics & numerical dataDeveloping Countries/statistics & numerical dataRespirationDeveloped CountriesArticlesGeneral Medicineacute respiratory distress syndromeLength of StayMiddle AgedRespiration ArtificialIntensive Care UnitsObservational Studies as Topiclnfectious Diseases and Global Health Radboud Institute for Health Sciences [Radboudumc 4]Length of Stay/statistics & numerical dataArtificialIntensive Care Units/statistics & numerical dataIncomeFemaleARDS
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