Diels-Alder Reactions of Tetraphenylcyclopentadienones in Nanochannels: Fabrication of Nanotubes from Hyperbranched Polyphenylenes

Solid-State Synthesis of “Bamboo-Like” and Straight Carbon Nanotubes by Thermolysis of Hexa-peri-hexabenzocoronene–Cobalt Complexes

Solid-State Pyrolyses of Metal Phthalocyanines: A Simple Approach towards Nitrogen-Doped CNTs and Metal/Carbon Nanocables

Solid-state pyrolysis of organometallic precursors has emerged as an alternative method for preparing carbon nanostructures such as carbon nanotubes (CNT) and carbon anions. The morphology of the tubes can be controlled by the nature of the precursors and the pyrolysis procedures, and micrometer long nanotubes, composed of metal carbide wires encased in a graphitic sheath. Cobalt phthalocyanine (CoPc) as well as iron phthalocyanine were pyrolyzed at different temperatures to obtain CNTs. HRTEM and energy-dispersion X-Ray analysis disclosed that the core consisted of long, iron-containing single crystals and that the core was fully surrounded by crystallized graphic carbon. Iron-filled carbo…

Exciton diffusion controlled quantum efficiency in hybrid dye sensitized solar cells.

Well-ordered and uniform titania nanoparticle arrays were synthesized using diblock copolymers as structure directing agents. High molecular weight copolymers of polystyrene-b-polyethylene oxide and poly(methylmethacrylate)-b-polyethylene oxide were used to control the distance between titania nanoparticles in the range of 20-60 nm. Using these titania nanoparticle arrays and regioregular poly(3-hexylthiophene), models for a dye sensitized photovoltaic cell were assembled, in which the interparticle spacing was systematically varied. In these simplified solar cells, the titania nanocrystals were surrounded by a continuous regioregular poly(3-hexylthiophene) phase. The spacing between the ti…

Probing the electronic state of a single coronene molecule by the emission from proximate fluorophores.

We measured electronic transitions of the 2D graphene-type molecule hexa-peri-hexabenzocoronene (HBC) at the single-molecule level. The large intersystem crossing rate and long triplet state lifetime in the range of seconds are prohibitive for direct single-molecule observation. By covalently coupling fluorescent acceptor molecules (perylenecarboximide, PMI) to HBC, efficient singlet energy transfer gives rise to strong PMI fluorescence. Confocal single-molecule fluorescence microscopy with two excitation colours matching the HBC and PMI transition frequencies, respectively, was conducted. Single HBC-6PMI molecules were readily observed via the PMI emission. It was found that after selectiv…

Solid-state pyrolysis of polyphenylene-metal complexes: A facile approach toward carbon nanoparticles

Novel polyphenylene-metal complexes with discotic, linear, and dendritic geometries are synthesized by using a facile approach consisting of reactions between Co2(CO)8 and ethynyl functionalities in dichloromethane. Various carbon nanoparticles (CNPs), including graphitic carbon nanotubes (CNTs), graphitic carbon rods, and carbon-metal hybrid particles are obtained from the solid-state pyrolysis of these complexes. The ultimate structures of the CNPs are found to be dependant on the structure and composition of the starting compounds. Precursors containing graphenes always result in graphitic CNTs in high yield, whereas dendritic precursors give rodlike carbon materials. Alternatively, line…

Self-assembly of amphiphilic imidazolium-based hexa-peri-hexabenzo-coronenes into fibreous aggregates

Imidazolium-based amphiphilic hexa-peri-hexabenzocoronenes were synthesized and shown to undergo ordered columnar self-assembly in solid-state as well as in solution to yield defined nanofibers upon solution drop casting onto solid substrate.

Uniform Carbon and Carbon/Cobalt Nanostructures by Solid-State Thermolysis of Polyphenylene Dendrimer/Cobalt Complexes

Benson, J. Am. Chem. Soc. 1962, 84, 3374. b) D. L. Jeanmaire, R. P. van Duyne, J. Am. Chem. Soc. 1976, 98, 4029. c) J. P. Gong, Y. Osada, Appl. Phys. Lett. 1992, 61, 2787. d) S. Liu, Y. Liu, D. Zhu, Thin Solid Films 1996, 280, 271. e) S. Liu, Y. Liu, P. Wu, D. Zhu, H. Tian, K. Chen, Thin Solid Films 1996, 289, 300. f) S. Liu, Y. Liu, P. Wu, D. Zhu, Chem. Mater. 1996, 8, 2779. [6] a) R. S. Potember, T. O. Poehler, D. O. Cowan, F. L. Carter, P. I. Brant, in Molecular Electronic Devices (Ed: F. L. Carter), Marcel Dekker, New York 1982. b) I. Ikemoto, J. M. Thomas, H. Kuroda, Bull. Chem. Soc. Jpn. 1973, 46, 2237. [7] a) A. M. Rao, D. Jacques, R. C. Haddon, W. Zhu, C. Bower, S. Jin, Appl. Phys. …

A water-soluble hexa-peri-hexabenzocoronene: synthesis, self-assembly and role as template for porous silica with aligned nanochannels

A water-soluble hexa-peri-hexabenzocoronene was prepared and shown to undergo ordered columnar self-assembly either in water solution or bulk and therefore served as template for the fabrication of porous silica with aligned nanochannels.

Carbonization of disclike molecules in porous alumina membranes: toward carbon nanotubes with controlled graphene-layer orientation.