0000000000336003
AUTHOR
S. Sholupov
Investigation of Hg resonance 184.9nm line profile in a low-pressure mercury–argon discharge
Abstract The line profiles of 184.9 nm Hg resonance line emitted from a Hg low-pressure high-frequency electrodeless discharge lamp, containing Hg 198 isotope, have been measured by means of a Zeeman scanning spectrometer at the mercury cold spot temperature values in the range of 0–23 °C. Two different methods were used to determine the real spectral line profile and to separate the instrument function: (i) solving the ill-posed inverse problem by means of the Tikhonov's regularization method; and (ii) the mathematical modelling by means of a non-linear multi-parameter chi-square fit. The real Hg 184.9 nm spectral line profiles, determined by both methods, are compared. Influence of instru…
<title>Advanced light sources for atomic absorption analysis</title>
High-frequency electrodeless light sources (HF EDLS) are widely used as bright radiators of narrow and intensive atomic and ionic spectral lines, covering the spectrum from VUV to IR. Main characteristics of HF EDLS are high emitted spectral line intensity, long service life, and in general, narrow spectral line shapes because of low-pressure of filling elements. In this work we give a short overview of the use of HF EDLS, containing Hg, Te, Se, Zn, Pb, As, Sb, Bi, Tl, In, Cd, Sn, in Zeeman Atomic absorption devices for assaying natural, drinking, waste and technical water as well as air, soil, food products and biological samples. The first steps are made for optimization of Ge, Ga, P, S, …