Dehydration of melt inclusions in olivine and implications for the origin of silica-undersaturated island-arc melts
Highlights • New experiments with melt inclusions in olivine at 1200 °C and 300 MPa. • Coupled behavior H2O and SiO2 in inclusions during re-hydration and dehydration. • SiO2 mobility results from formation/destruction of metal vacant olivine. • SiO2-undersaturated arc melt inclusions may originate by dehydration. • New method to assess initial H2O in dehydrated inclusions. Abstract Primary subduction-related magmas build up modern continental crust and counterbalance massive recycling of crustal material into the deep mantle occurring at this tectonic setting. Melt inclusions in Mg-rich olivine are believed to be the best probes of primary subduction-related melts. However, unexpectedly, m…
Experimental calibration and implications of olivine-melt vanadium oxybarometry for hydrous basaltic arc magmas
The strong dependence of vanadium partitioning between olivine and silicate melt (DVOl-M) on redox conditions (fO2) can be used as sensitive oxybarometer in magmatic systems. Here we extend the experimental database on DVOl-M, obtained so far at high temperatures (mainly above 1250 °C), to lower temperatures that are typical for island-arc basalts. Crystallization experiments were performed using a composition from Mutnovsky volcano (Kamchatka), and the investigated temperature, pressure, and oxygen fugacity ranges were 1025–1150 °C, 0.1 and 0.3 GPa, and ΔQFM of –0.5 to +3.2, respectively. The water content in melts ranged from 0.6 to ∼6.5 wt% H2O. The data demonstrate a strong negative cor…
In situ quantification of the nitrogen content of olivine-hosted melt inclusions from Klyuchevskoy volcano (Kamchatka): Implications for nitrogen recycling at subduction zones
International audience; Assessing the N content of arc magmas and their mantle source remains a challenge because the volatile element composition of melts and gases can be modified during magma ascent, storage, and eruption. Given that melt inclusions (MIs) in Mg-rich olivine represent the best proxies for primary arc melts, we applied, for the first time, an in situ high-resolution secondary ion mass spectrometry (SIMS) method to determine the N concentration in olivine-hosted MIs from Klyuchevskoy volcano in Kamchatka. To reverse the effects of post-entrapment modification processes (i.e., exsolution of volatiles into a fluid bubble), the MIs were partially to completely homogenized at h…
Composition, crystallization conditions and genesis of sulfide-saturated parental melts of olivine-phyric rocks from Kamchatsky Mys (Kamchatka, Russia)
Highlights • Parental melts of sulfide-bearing KM rocks have near primary MORB-like composition. • Crystallization of these S-saturated melts occurred in near-surface conditions. • Extensive fractionation and crustal assimilation are not the causes of S-saturation. • S content in melts can be restored by accounting for daughter sulfide globules. Abstract Sulfide liquids that immiscibly separate from silicate melts in different magmatic processes accumulate chalcophile metals and may represent important sources of the metals in Earth's crust for the formation of ore deposits. Sulfide phases commonly found in some primitive mid-ocean ridge basalts (MORB) may support the occurrence of sulfide …