0000000000345237
AUTHOR
Aurélien Eglinger
Geochemical fingerprints of brannerite (UTi 2 O 6 ): an integrated study
AbstractBrannerite (UTi2O6) is among the major uranium-bearing minerals found in ore deposits, however as it has been long considered as a refractory mineral for leaching it is currently disregarded in ore deposits. Brannerite is found in a variety of geological environments with the most common occurrences being hydrothermal and pegmatitic. On the basis of scanning electron microscopy observations coupled with electron probe micro-analyses and laser ablation inductively-coupled plasma mass spectrometer analyses, this study describes the morphological features and the major- and trace-element abundances of brannerite samples from five hydrothermal and five pegmatitic localities across the w…
The Adamawa-Yadé domain, a piece of Archaean crust in the Neoproterozoic Central African Orogenic belt (Bafia area, Cameroon)
Abstract New field observations, ages and geochemical data are presented for the Adamawa-Yade domain, forming part of Central African Orogenic Belt in Cameroon. This belt delineates the northern margin of the Congo craton and is part of the Braziliano/Pan-African orogenic system, which was formed during amalgamation of the West Gondwana continent at the end of the Neoproterozoic. U–Pb dating indicates that the protoliths of some orthogneisses from the Adamawa-Yade domain were emplaced during three distinct periods. Tonalite-Trondhjemite-Granodiorite (TTG) suites in the Makenene area intruded at ca. 3.0–2.5 Ga, and were affected by partial melting at ca. 2.08–2.07 Ga, during the Eburnean oro…
Tectono-metamorphic evolution of the internal zone of the Pan-African Lufilian orogenic belt (Zambia): Implications for crustal reworking and syn-orogenic uranium mineralizations
Abstract The internal zone of the Pan-African Lufilian orogenic belt (Zambia) hosts a dozen uranium occurrences mostly located within kyanite micaschists in a shear zone marking the contact between metasedimentary rocks attributed to the Katanga Neoproterozoic sedimentary sequence and migmatites coring domes developed dominantly at the expense of the pre-Neoproterozoic basement. The P–T–t–d paths reconstructed for these rocks combining field observations, microstructural analysis, metamorphic petrology and thermobarometry and geochronology indicate that they have recorded burial and exhumation during the Pan-African orogeny. Both units of the Katanga metasedimentary sequence and pre-Katanga…
Direct synthesis of pure brannerite UTi2O6
International audience; A new method based on the precipitation of uranium(IV) and titanium(IV) hydroxide precursors was developed to prepare pure brannerite UTi2O6 samples. In fact, U(IV) dissolved in HCl (6 mol L−1) was mixed to Ti (IV) alkoxyde before a basification step with an excess of NH4OH to obtain a highly reactive nanometric (U,Ti)(OH)4 powder. The obtained powder was then dried under vacuum, pressed into pellets and finally fired at 1300 °C. This method led to the formation of pure brannerite in contrast to previous reported protocols, which showed the formation of impurities such us UO2 and TiO2. The refined unit cell parameters of UTi2O6 led to a = 9.8113(2) Å, b = 3.7681(1) Å…
Solubility of Monazite–Cheralite and Xenotime in Granitic Melts, and Experimental Evidence of Liquid–Liquid Immiscibility in Concentrating REE
Abstract We provide new experimental data on monazite, xenotime and U–Th-bearing cheralite solubility in slightly peralkaline to peraluminous granitic melts using dissolution and reverse (i.e. recrystallization after dissolution) experiments in water-saturated and flux-bearing (P + F + Li) granitic melts, at 800 °C and 200 MPa. Although a positive correlation between rare earth element (REE) solubility and melt peralkalinity is confirmed, monazite solubilities reported here are much lower than the values previously published. We suggest that the presence of elevated phosphorus concentrations in our melts depresses monazite solubility, principally because phosphorus complexes with Al and alk…
Reply to comment by Ngako and Njonfang on “The Adamawa-Yade domain, a piece of Archaean crust in the Neoproterozoic Central African Orogenic belt (Bafia area, Cameroon)”, by Jacqueline Tchakounté et al., Precambrian Research 299 (2017) 210–229
Abstract V. Ngako and E. Njonfang addressed in their comment an interesting and debated issue about the collision geodynamics of the Pan-African Central African Orogenic Belt (CAOB) in Cameroon. However, the reason for this comment is still not clear to us since it mainly deals with issues far away from the scope of our study, namely, the pre-collisional set up of the belt. The comment raises two main points – the reworking process during plate collision and the Pan-African strain pattern – not discussed in our paper for the simple reason that it was not our goal and because our data set does not even allow such discussion. Having said that, the comment gives us the opportunity to clarify o…