Bio-chronostratigraphic calibration of the Upper Carnian-Lower Norian magnetostratigraphic scale at Pizzo Mondello (Sicani Mountains, Sicily).

Sr isotope variations in the Upper Triassic succession at Pizzo Mondello, Sicily: Constraints on the timing of the Cimmerian Orogeny

Abstract The Late Triassic Cimmerian Orogeny was a result of the final closure of the Palaeotethys Ocean and the accretion of Gondwana-derived (Cimmerian) continents to southern Eurasia. Determining the timing of the Cimmerian Orogeny is crucial to our understanding of the large-scale climate changes driven by the uplift of the Cimmerian Mountains. Here we present stratigraphic variations in 87Sr/86Sr values of Upper Triassic pelagic limestone from the Pizzo Mondello section, Sicily, Italy, that constrain the timing of uplift of the Cimmerian Mountains. The 87Sr/86Sr values remain relatively constant in the lower part of the section, decreasing slightly in the Tuvalian (upper Carnian) and L…

An enormous sulfur isotope excursion indicates marine anoxia during the end-Triassic mass extinction

The role of ocean anoxia as a cause of the end-Triassic marine mass extinction is widely debated. Here, we present carbonate-associated sulfate δ34S data from sections spanning the Late Triassic–Early Jurassic transition, which document synchronous large positive excursions on a global scale occurring in ~50 thousand years. Biogeochemical modeling demonstrates that this S isotope perturbation is best explained by a fivefold increase in global pyrite burial, consistent with large-scale development of marine anoxia on the Panthalassa margin and northwest European shelf. This pyrite burial event coincides with the loss of Triassic taxa seen in the studied sections. Modeling results also indica…

Mercury contents and isotope ratios from diverse depositional environments across the Triassic–Jurassic Boundary: Towards a more robust mercury proxy for large igneous province magmatism

Abstract Mercury is gaining prominence as a proxy for large igneous province (LIP) volcanism in the sedimentary record. Despite temporal overlap between some mass extinctions and LIPs, the precise timing of magmatism relative to major ecological and environmental change is difficult to untangle, especially in marine settings. Changes in the relative contents of Hg in sedimentary rocks through time, or ‘Hg anomalies’, can help resolve the timing of LIP activity and marine extinctions. However, major questions remain unanswered about the fidelity of Hg as a proxy for LIP magmatism. In particular, depositional (e.g., redox) and post-depositional (e.g., oxidative weathering) processes can affec…