0000000000347679

AUTHOR

Sophie Fournier

showing 30 related works from this author

Synthesis and characterization of novel quinolyl porphyrins as receptors. Study of their association with halophenols and 4nitrophenol as a reference

2020

International audience; In this work, new receptors built on the porphyrin scaffold were synthesized for halophenols recognition. A quinolyl group was introduced on the porphyrin's periphery as binding site, to form two series of molecules based on two distinct porphyrin frames and which were obtained in free base and zinc forms. The binding between these porphyrin based receptors and halophenols (2,3,4,6tetrachlorophenol, 2,4,6-trichlorophenol or 2,4,6-tribromophenol) was studied. As established by 1 H NMR spectroscopy, the binding constants are in the range of two-digit numbers, which value is correlated with the porphyrin structure (substitutive pattern, form of the free base or Zn II co…

Inorganic Chemistrychemistry.chemical_compoundchemistry010405 organic chemistrychemistry.chemical_element4-Nitrophenol[CHIM.COOR]Chemical Sciences/Coordination chemistryZinc010402 general chemistryReceptor01 natural sciencesCombinatorial chemistry0104 chemical sciences
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A glassy carbon electrode modified by a triply-fused-like Co( ii ) polyporphine and its ability for sulphite oxidation and detection

2018

This article presents a Co(II) polyporphine conductive polymer easily and rapidly obtained (less than 2 h 30 min) on the surface of a glassy carbon electrode from the transformation of an initial Mg(II) porphine solution in a four-step process (including electrochemical and chemical stages). The intimate molecular structure is argued on the basis of the electrochemical response of the modified electrode, as well as its surface characterization. Owing to its apparent stability in water over potential cycling and its high density in active Co(II) centers, the electrosynthesized film shows its ability to catalyze sulphite oxidation in aqueous solutions. The mechanism of this molecular catalysi…

Conductive polymerDetection limitAqueous solutionChemistry[CHIM.ORGA]Chemical Sciences/Organic chemistryGlassy carbon electrodeInorganic chemistry02 engineering and technologyGeneral Chemistry[CHIM.MATE]Chemical Sciences/Material chemistry010402 general chemistry021001 nanoscience & nanotechnologyElectrochemistry01 natural sciencesCatalysis0104 chemical sciencesCatalysis[CHIM.ANAL]Chemical Sciences/Analytical chemistryElectrodeMaterials ChemistryMolecule[CHIM.COOR]Chemical Sciences/Coordination chemistry0210 nano-technology
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Kinetic and Electrochemical Studies of the Oxidative Addition of Demanding Organic Halides to Pd(0): the Efficiency of Polyphosphane Ligands in Low P…

2013

International audience; Oxidative addition (OA) of organic halides to palladium(0) species is a fundamental reaction step which initiates the C–C bond formation catalytic processes typical of Pd(0)/Pd(II) chemistry. The use of structurally congested polyphosphane ligands in palladium-catalyzed C–C bond formation has generated very high turnover numbers (TONs) in topical reactions such as Heck, Suzuki, Sonogashira couplings, and direct sp2C–H functionalization. Herein, the OA of aryl bromides to Pd(0) complexes stabilized by ferrocenylpolyphosphane ligands L1 (tetraphosphane), L2 (triphosphane), and L3 (diphosphane) is considered. The investigation of kinetic constants for the addition of Ph…

010405 organic chemistryReaction stepInorganic chemistrychemistry.chemical_elementHalide[CHIM.CATA]Chemical Sciences/CatalysisBond formation010402 general chemistryPhotochemistryKinetic energyElectrochemistry01 natural sciencesOxidative addition0104 chemical sciencesCatalysisInorganic Chemistry[ CHIM.CATA ] Chemical Sciences/CatalysischemistryPhysical and Theoretical ChemistryPalladium
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Gold(I) Complexes Nuclearity in Constrained Ferrocenyl Diphosphines: Dramatic Effect in Gold‐Catalyzed Enyne Cycloisomerization

2020

International audience; Di-tert-butylated-bis(phosphino)ferrocene ligands bearing phosphino substituents R (R=phenyl, cyclohexyl, isopropyl, mesityl, or furyl) allow tuning the selective formation of Au(I) halide complexes. Thus, dinuclear linear twocoordinate, but also rare mononuclear trigonal three-coordinate and tetrahedral four-coordinate complexes were formed upon tuning of the conditions. Both Au(I) chloride and rarer Au(I) iodide complexes were synthesized, and their X-ray diffraction analysis are reported. The significance of the control of structure and nuclearity in Au(I) complexes is further illustrated herein by its strong effect on the efficiency and selectivity of gold-cataly…

Enyne010405 organic chemistryChemistryOrganic ChemistryCationic polymerizationRegioselectivityGeneral Chemistry[CHIM.CATA]Chemical Sciences/Catalysis010402 general chemistry01 natural sciencesBiochemistryMedicinal chemistryCycloaddition0104 chemical scienceschemistry.chemical_compoundCycloisomerizationFerroceneIntramolecular forceDiphosphines
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Aminomethyl-Substituted Ferrocenes and Derivatives: Straightforward Synthetic Routes, Structural Characterization, and Electrochemical Analysis

2013

A variety of aminomethyl-substituted ferrocenes and the parent compounds (iminomethyl)ferrocenes, azaferrocenophanes, and diferrocenylamines can be selectively synthesized from reductive amination of 1,1′-diformylferrocene or formylferrocene. The optimized one- or two-step reactions have delivered 13 new compounds, isolated in 65–97% yields, which include tertiary (ferrocenylmethyl)amines and azaferrocenophanes by using NaBH(OAc)3 as a mild reducing agent and (iminomethyl)ferrocenes and secondary (ferrocenylmethyl)amines by using LiAlH4. X-ray structures of representative members of these ferrocene derivative families have evidenced the preferred conformation adopted by ferrocene backbones,…

Steric effectsNitromethaneReducing agentChemistryOrganic ChemistryElectrochemistryReductive aminationCombinatorial chemistryInorganic Chemistrychemistry.chemical_compoundFerroceneOrganic chemistryFerrocene derivativesPhysical and Theoretical ChemistryCyclic voltammetryOrganometallics
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Electrosynthesis as a powerful method for the generation of catalytic intermediates: efficient isolation of a palladium aryl halide oxidative additio…

2011

International audience; Polyphosphane ligands of controlled conformation promote highly efficient palladium-catalyzed cross-coupling reactions. Electrosynthesis has been used as a new straightforward method to obtain important intermediates in the search for a better mechanistic understanding. As a proof of concept, the facile synthesis of a phenyl iodopalladium(II) complex (2) was conducted at the electrolysis scale from a readily electrogenerated unstable Pd0 precursor.

chemistry.chemical_classificationReaction mechanism010405 organic chemistryoxidative additionAryl halideOrganic Chemistrychemistry.chemical_elementGeneral Chemistry[CHIM.CATA]Chemical Sciences/Catalysis010402 general chemistryElectrosynthesispalladium01 natural sciencesOxidative additionCatalysis0104 chemical sciencesCatalysis[ CHIM.CATA ] Chemical Sciences/Catalysisreaction mechanismselectrosynthesischemistryOrganic chemistryaryl halidePalladium
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CCDC 1983790: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(11'-bis(dicyclohexylphosphino)-33'-di-t-butylferrocene)-iodo-gold(i)Experimental 3D Coordinates
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CCDC 1919134: Experimental Crystal Structure Determination

2020

Related Article: Julie Echaubard, Asmae Bousfiha, Mathieu Berthelot, Julien Roger, Paul Fleurat-Lessard, Hélène Cattey, Sophie Fournier, Charles H. Devillers, Dominique Lucas|2020|Eur.J.Inorg.Chem.|2020|551 |doi:10.1002/ejic.201900849

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersaqua-[515-bis(4-methylphenyl)-10-phenyl-20-(quinolin-8-yl)porphyrinato]-zinc 4-nitrophenolExperimental 3D Coordinates
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CCDC 1919135: Experimental Crystal Structure Determination

2020

Related Article: Julie Echaubard, Asmae Bousfiha, Mathieu Berthelot, Julien Roger, Paul Fleurat-Lessard, Hélène Cattey, Sophie Fournier, Charles H. Devillers, Dominique Lucas|2020|Eur.J.Inorg.Chem.|2020|551 |doi:10.1002/ejic.201900849

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters246-trichlorophenol 515-bis(4-methylphenyl)-10-phenyl-20-(quinolin-8-yl)porphyrin unknown solvateExperimental 3D Coordinates
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CCDC 980179: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallography11'-(((benzy)amino)dimethyl)ferroceneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 980175: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallographyCrystal System11'-bis(piperidin-1-ylmethyl)ferroceneCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1983787: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallography(11'-bis(diphenylphosphino)-33'-di-t-butylferrocene)-iodo-gold(i) dichloromethane unknown solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 980177: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

11'-(((4-phenyl-n-butyl)amino)dimethyl)ferroceneSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1983797: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-11'-bis(dimesitylphosphino)-33'-di-t-butylferrocene)-di-iodo-di-gold(i) dichloromethane solvateExperimental 3D Coordinates
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CCDC 980178: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates11'-(((n-butyl)amino)dimethyl)ferrocene
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CCDC 1983798: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(11'-bis(bis(5-methylfur-2-yl)phosphino)-33'-di-t-butylferrocene)-gold(i) chlorideExperimental 3D Coordinates
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CCDC 1983791: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(11'-bis(dicyclohexylphosphino)-33'-di-t-butylferrocene)-chloro-gold(i) dichloromethane solvateExperimental 3D Coordinates
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CCDC 980174: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallographyCrystal SystemCrystal Structure11'-bis(pyrrolidin-1-ylmethyl)ferroceneCell ParametersExperimental 3D Coordinates
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CCDC 980176: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters11'-bis((dibenzylamino)methyl)ferroceneExperimental 3D Coordinates
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CCDC 1983795: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-11'-bis(dimesitylphosphino)-33'-di-t-butylferrocene)-di-chloro-di-gold(i) cyclohexane solvateExperimental 3D Coordinates
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CCDC 1983789: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-11'-bis(dicyclohexylphosphino)-33'-di-t-butylferrocene)-di-iodo-di-gold(i)Experimental 3D Coordinates
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CCDC 980180: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters11'-bis((t-butylamino)methyl)ferroceneExperimental 3D Coordinates
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CCDC 1983788: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-11'-bis(dicyclohexylphosphino)-33'-di-t-butylferrocene)-dichloro-di-gold(i) dichloromethane solvateExperimental 3D Coordinates
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CCDC 1983796: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(mu-11'-bis(dimesitylphosphino)-33'-di-t-butylferrocene)-dichloro-di-gold(i) unknown solvate
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CCDC 1983794: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallographyCrystal System(11'-bis(di-prop-2-ylphosphino)-33'-di-t-butylferrocene)-iodo-gold(i)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1983793: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-11'-bis(di-prop-2-ylphosphino)-33'-di-t-butylferrocene)-di-iodo-di-gold(i)Experimental 3D Coordinates
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CCDC 1983785: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallography(mu-11'-bis(diphenylphosphino)-33'-di-t-butylferrocene)-dichloro-di-gold(i) dichloromethane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 980181: Experimental Crystal Structure Determination

2014

Related Article: Nejib Dwadnia, Fatima Allouch, Nadine Pirio, Julien Roger, Hélène Cattey, Sophie Fournier, Marie-Josée Penouilh, Charles H. Devillers, Dominique Lucas, Daoud Naoufal, Ridha Ben Salem, and Jean-Cyrille Hierso|2013|Organometallics|32|5784|doi:10.1021/om400317s

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters11-(mu~2~-(n-butylamino)dimethyl)-diferroceneExperimental 3D Coordinates
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CCDC 1983792: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates(mu-11'-bis(di-prop-2-ylphosphino)-33'-di-t-butylferrocene)-di-chloro-di-gold(i)
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CCDC 1983786: Experimental Crystal Structure Determination

2020

Related Article: Tuan‐Anh Nguyen, Julien Roger, Houssein Nasrallah, Vincent Rampazzi, Sophie Fournier, Hélène Cattey, E. Daiann Sosa Carrizo, Paul Fleurat‐Lessard, Charles H. Devillers, Nadine Pirio, Dominique Lucas, Jean‐Cyrille Hierso|2020|Chem.Asian J.|15|2879|doi:10.1002/asia.202000579

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-11'-bis(diphenylphosphino)-33'-di-t-butylferrocene)-dichloro-di-gold(i) methanol solvateExperimental 3D Coordinates
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