6533b861fe1ef96bd12c50b7
RESEARCH PRODUCT
Electrosynthesis as a powerful method for the generation of catalytic intermediates: efficient isolation of a palladium aryl halide oxidative addition product.
Sophie FournierJean-cyrille HiersoHélène CatteyHenri DoucetCaihong LuoCharles H. DevillersDominique LucasVeronika A. Zinovyevasubject
chemistry.chemical_classificationReaction mechanism010405 organic chemistryoxidative additionAryl halideOrganic Chemistrychemistry.chemical_elementGeneral Chemistry[CHIM.CATA]Chemical Sciences/Catalysis010402 general chemistryElectrosynthesispalladium01 natural sciencesOxidative additionCatalysis0104 chemical sciencesCatalysis[ CHIM.CATA ] Chemical Sciences/Catalysisreaction mechanismselectrosynthesischemistryOrganic chemistryaryl halidePalladiumdescription
International audience; Polyphosphane ligands of controlled conformation promote highly efficient palladium-catalyzed cross-coupling reactions. Electrosynthesis has been used as a new straightforward method to obtain important intermediates in the search for a better mechanistic understanding. As a proof of concept, the facile synthesis of a phenyl iodopalladium(II) complex (2) was conducted at the electrolysis scale from a readily electrogenerated unstable Pd0 precursor.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2011-08-29 |