0000000001150411

AUTHOR

Caihong Luo

showing 2 related works from this author

Electrosynthesis as a powerful method for the generation of catalytic intermediates: efficient isolation of a palladium aryl halide oxidative additio…

2011

International audience; Polyphosphane ligands of controlled conformation promote highly efficient palladium-catalyzed cross-coupling reactions. Electrosynthesis has been used as a new straightforward method to obtain important intermediates in the search for a better mechanistic understanding. As a proof of concept, the facile synthesis of a phenyl iodopalladium(II) complex (2) was conducted at the electrolysis scale from a readily electrogenerated unstable Pd0 precursor.

chemistry.chemical_classificationReaction mechanism010405 organic chemistryoxidative additionAryl halideOrganic Chemistrychemistry.chemical_elementGeneral Chemistry[CHIM.CATA]Chemical Sciences/Catalysis010402 general chemistryElectrosynthesispalladium01 natural sciencesOxidative additionCatalysis0104 chemical sciencesCatalysis[ CHIM.CATA ] Chemical Sciences/Catalysisreaction mechanismselectrosynthesischemistryOrganic chemistryaryl halidePalladium
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CCDC 814626: Experimental Crystal Structure Determination

2011

Related Article: V.A.Zinovyeva, Caihong Luo, S.Fournier, C.H.Devillers, H.Cattey, H.Doucet, J.-C.Hierso, D.Lucas|2011|Chem.-Eur.J.|17|9901|doi:10.1002/chem.201100629

Space GroupCrystallographyCrystal SystemCrystal Structure(44'-Di-t-butyl-11'22'-tetrakis(diphenylphosphino)ferrocene-PP')-iodo-phenyl-palladium(ii) dichloromethane solvateCell ParametersExperimental 3D Coordinates
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