0000000000353344

AUTHOR

ŁUkasz Hetmańczyk

0000-0001-6725-9859

showing 2 related works from this author

Low temperature measurements by infrared spectroscopy in $CoFe_2O_4$ ceramic

2012

In this paper results of new far-infrared and middle-infrared measurements (wavenumber range of 4000cm-1 - 100cm-1) in the range of the temperature from 300K to 8K of the CoFe2O4 ceramic are presented. The bands positions and their shapes are the same in the wide temperature range. The quality of the sample was investigated by X-ray, EDS and EPMA studies. The CoFe2O4 reveals the cubic structure (Fd-3m) in the temperature range from 85K to 360 K without any traces of distortion. On the current level of knowledge the polycrystalline CoFe2O4 does not exhibit phase transition in the temperature range from 8 K to 300 K.

Phase transitionMaterials scienceQC1-999FT-FIRft-firAnalytical chemistryFOS: Physical sciencesGeneral Physics and AstronomyInfrared spectroscopyElectron microprobeTemperature measurement$CoFe_2O_4$CeramicCondensed Matter - Materials ScienceRange (particle radiation)Physicscobalt spinel ferriteMaterials Science (cond-mat.mtrl-sci)Atmospheric temperature rangecofe2o4visual_artinfraredvisual_art.visual_art_mediumCrystalliteft-mirFT-MIR
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Investigations of Low Temperature Phase Transitions in BiFeO3Ceramic by Infrared Spectroscopy

2011

In this paper, results of new infrared FIR-MIR measurements (wavenumber range of 4000–100 cm−1) in the range of the temperature 300 ÷ 8 K of the BiFeO3 ceramic are presented. Below 200 K only one symmetric band at ca. 800 cm−1 is visible. The full width at half maximum of this band decreases exponentially on cooling. The shape of the band at ca. 545 cm−1connected with A1 (TO) mode also changes between 60–40 K, this is in the vicinity of the phase transition at 50 K. Initially a broad band reveals its components as shoulder bands. Theirs FWHM decrease with cooling.

Phase transitionMaterials sciencemultiferroicsInfraredbusiness.industryInfrared spectroscopyH bandbismuth ferriteCondensed Matter PhysicsMolecular physicsElectronic Optical and Magnetic MaterialsFull width at half maximumchemistry.chemical_compoundOpticschemistryvisual_artBiFeO_3IRvisual_art.visual_art_mediumWavenumberCeramicbusinessBismuth ferriteFerroelectrics
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