Experimental calibration and implications of olivine-melt vanadium oxybarometry for hydrous basaltic arc magmas

The strong dependence of vanadium partitioning between olivine and silicate melt (DVOl-M) on redox conditions (fO2) can be used as sensitive oxybarometer in magmatic systems. Here we extend the experimental database on DVOl-M, obtained so far at high temperatures (mainly above 1250 °C), to lower temperatures that are typical for island-arc basalts. Crystallization experiments were performed using a composition from Mutnovsky volcano (Kamchatka), and the investigated temperature, pressure, and oxygen fugacity ranges were 1025–1150 °C, 0.1 and 0.3 GPa, and ΔQFM of –0.5 to +3.2, respectively. The water content in melts ranged from 0.6 to ∼6.5 wt% H2O. The data demonstrate a strong negative cor…