showing 3 related works from this author
Crystal structure of the coordination polymer [FeIII2{PtII(CN)4}3]
2015
[EN] The title complex, poly[dodeca--cyanido-diiron(III)triplatinum(II)], [FeIII2{PtII(CN)4}3], has a three-dimensional polymeric structure. It is built-up from square-planar [PtII(CN)4] 2 anions (point group symmetry 2/m) bridging cationic [FeIIIPtII(CN)4] + 1 layers extending in the bc plane. The FeII atoms of the layers are located on inversion centres and exhibit an octahedral coordination sphere defined by six N atoms of cyanide ligands, while the PtII atoms are located on twofold rotation axes and are surrounded by four C atoms of the cyanide ligands in a square-planar coordination. The geometrical preferences of the two cations for octahedral and square-planar coordination, respectiv…
Sublimable complexes with spin switching: chemical design, processing as thin films and integration in graphene-based devices
2023
Among the different types of switchable molecular compounds, sublimable Fe(II) SCO molecules provide a suitable platform to develop smart devices that respond to external stimuli. Here we report the synthesis, crystallographic structure and magnetic properties of three new neutral Fe(II) SCO molecules belonging to the {Fe[H2B(pz)2]2(L)} family with bidentate-alpha-diimine ligands L = 3-(pyridin-2-yl)-[1,2,3]triazolo[1,5-a]pyridine (tzpy), 5,5,6,6-tetrahydro-4H,4H-2,2-bi(1,3-thiazine) (btz) and 4,4,5,5-tetrahydro-2,2-bithiazole (bt) (1, 2 and 3, respectively), as well as two solvated forms of 1 and 3. All three desolvated compounds present thermal- and light-induced SCO transitions with diff…
Coordination Polymers
2018
Este documento ha sido elaborado en el marco de un proyecto de Renovación de Metodologías Docentes concedido por el servicio de Formación Permanente de la Universitat de Valencia (UV-SFPIE_RMD17-725369) Este documento forma parte de la asignatura Química Inorgánica Avanzada impartida en el Máster Universitario en Química This document is part of the course Advanced Inorganic Chemistry belonging to the Master in Chemistry