Global frequency and intensity analysis of the / / / band system of 12 C 2 H 4 at 10 μm using the D 2h Top Data System

Abstract A global frequency and intensity analysis of the infrared tetrad of 12C2H4 located in the 600 – 1500 cm − 1 region was carried out using the tensorial formalism developed in Dijon for X2Y4 asymmetric-top molecules. It relied on spectroscopic information available in the literature and retrieved from high-resolution Fourier transform infrared spectra recorded in Brussels in the frame of either the present or previous work. In particular, 645 and 131 line intensities have been respectively measured for the weak ν10 and ν4 bands. Including the Coriolis interactions affecting the upper vibrational levels 101, 71, 41 and 121, a total of 10 757 line positions and 1645 line intensities ha…