Chalcogen adsorption and surface magnetism

Abstract Investigations concerning the electronic and magnetic properties of oxygen and sulfur adsorbed on magnetized surfaces were carried out by means of angle and spin resolving photoelectron spectroscopy. Iron(110), a polycrystalline iron alloy, and an amorphous metallic glass (Fe 79 B 16 Si 5 ) served as ferromagnetic substrates. Exchange splittings of the O 2p and S 3p derived levels could be detected, demonstrating a magnetic coupling between the chemisorbate and iron. This observation presents a prerequisite for an induced magnetic moment within the adsorbate overlayer. For sulfur an adsorbate-induced structure only in the minority spin channel near the Fermi level was observed whic…