0000000000372898
AUTHOR
A. Riccio
Antioxidant Activity of All-trans-retinol in Homogeneous Solution and in Phosphatidylcholine Liposomes
A kinetic quantification of the lipoperoxyl radical-scavenging activity of all-trans-retinol has been carried out in homogeneous solution, when radicals were produced from the oxidation of methyl linoleate in methanol, initiated by the lipid-soluble 2,2′-azobis (2,4-dimethyl-valeronitrile) (AMVN) as well as in a soybean phosphatidylcholine membrane model, in which peroxidation was induced either by AMVN or the hydrophylic 2,2′-azobis(2-amidinopropane)hydrochloride (AAPH). The physical microenvironment contributes to the determination of antioxidant efficiency of all-trans-retinol. In homogeneous solution the kinetic constant kinh is 3.5 × 105 M-1 s-1 and appears of the same order of magnitu…
Numerical and Experimental Study of Defects Evolution in a Composites Wing Box Under Compressive Loads
Due to their high specific strength and stiffness, Carbon Fibres Reinforced Plastics (CFRP) are commonly considered suitable for aerospace structural applications. However, their failure mechanisms are not completely predictable and this is the main reason why the CFRP integration in the aerospace industry has been generally slow in the last twenty years. Indeed, the lack of robust numerical tools, able to take into account the damage tolerance of composite structures, has led to over-conservative designs, not fully realising the promised economic benefits of composites materials. The Project MACMES (Damage Management of Aircraft Composite Structures Monitored by Embedded Sensors), funded b…