0000000000374293

AUTHOR

Weihao Weng

showing 3 related works from this author

Niobium phosphates as new highly selective catalysts for the oxidative dehydrogenation of ethane

2011

Several niobium phosphate phases have been prepared, fully characterized and tested as catalysts for the selective oxidation of ethane to ethylene. Three distinct niobium phosphate catalysts were prepared, and each was comprised predominantly of a different bulk phase, namely Nb(2)P(4)O(15), NbOPO(4) and Nb(1.91)P(2.82)O(12). All of the niobium phosphate catalysts showed high selectivity towards ethylene, but the best catalyst was Nb(1.91)P(2.82)O(12), which was produced from the reduction of niobium oxide phosphate (NbOPO(4)) by hydrogen. It was particularly selective for ethylene, giving ca. 95% selectivity at 5% conversion, decreasing to ca. 90% at 15% conversion, and only produced low l…

EthyleneHydrogenInorganic chemistryNiobiumGeneral Physics and Astronomychemistry.chemical_elementPhosphateCatalysischemistry.chemical_compoundchemistryNiobium oxideDehydrogenationPhysical and Theoretical ChemistrySelectivityPhysical Chemistry Chemical Physics
researchProduct

The significance of the order of impregnation on the activity of vanadia promoted palladium-alumina catalysts for propane total oxidation

2011

The increased activity of alumina-supported palladium catalysts promoted with vanadium oxide has been investigated. Three different vanadium promoted Pd/Al2O3 catalysts with the same composition but synthesized employing sequential and co-impregnation were tested for the total oxidation of propane. The order of impregnation was critical to produce high activity catalysts. Vanadium and palladium co-impregnation on the Al2O3 support led to the most active catalyst, whereas the step-wise impregnated catalysts show a catalytic performance similar to or slightly better than unpromoted palladium catalysts. The high activity of the co-impregnated catalysts is related to the particle size and oxida…

Oxidation stateChemistryCatalyst supportInorganic chemistrychemistry.chemical_elementVanadiumParticle sizeRedoxCatalysisVanadium oxideCatalysisPalladiumCatalysis Science & Technology
researchProduct

Structural characterization of Niobium Phosphate Catalysts used for the Oxidative Dehydrogenation of Ethane to Ethylene

2011

Extended abstract of a paper presented at Microscopy and Microanalysis 2011 in Nashville, Tennessee, USA, August 7–August 11, 2011.

EthyleneInorganic chemistryNiobiumchemistry.chemical_elementOxidative phosphorylationPhosphateCharacterization (materials science)Catalysischemistry.chemical_compoundchemistryOrganic chemistryDehydrogenationQDInstrumentation
researchProduct