0000000000379924
AUTHOR
James R. Lewis
The VST Photometric Hα Survey of the Southern Galactic Plane and Bulge (VPHAS+)
The VST Photometric Halpha Survey of the Southern Galactic Plane and Bulge (VPHAS+) is surveying the southern Milky Way in u, g, r, i and Halpha at 1 arcsec angular resolution. Its footprint spans the Galactic latitude range -5 < b < +5 at all longitudes south of the celestial equator. Extensions around the Galactic Centre to Galactic latitudes +/-10 bring in much of the Galactic Bulge. This ESO public survey, begun on 28th December 2011, reaches down to 20th magnitude (10-sigma) and will provide single-epoch digital optical photometry for around 300 million stars. The observing strategy and data pipelining is described, and an appraisal of the segmented narrowband Halpha filter in us…
Molecular structures of Se(SCH3)2 and Te(SCH3)2 using gas-phase electron diffraction and ab initio and DFT geometry optimisations
The molecular structures of Se(SCH3)2 and Te(SCH3)2 were investigated using gas-phase electron diffraction (GED) and ab initio and DFT geometry optimisations. While parameters involving H atoms were refined using flexible restraints according to the SARACEN method, parameters that depended only on heavy atoms could be refined without restraints. The GED-determined geometric parameters (rh1) are: rSe-S 219.1(1), rS-C 183.2(1), rC-H 109.6(4) pm; S-Se-S 102.9(3), Se-S-C 100.6(2), S-C-H (mean) 107.4(5), S-Se-S-C 87.9(20), Se-S-C-H 178.8(19)° for Se(SCH3)2, and rTe-S 238.1(2), rS-C 184.1(3), rC-H 110.0(6) pm; S-Te-S 98.9(6), Te-S-C 99.7(4), S-C-H (mean) 109.2(9), S-Te-S-C 73.0(48), Te-S-C-H 180.…