0000000000384728
AUTHOR
J. Daubert
Elastic constants in RbI, determined by inelastic neutron scattering
Long-wavelength acoustic phonons have been studied in the whole (100)-plane of RbI at 295 K by means of inelastic neutron scattering. The raw data have been corrected for resolution effects taking into account the curvature of the dispersion surface and variations of the mode eigenvectors. The shifts of the neutron groups due to these resolution effects are discussed in detail. The analysis of the experimental results gives for the zero sound elastic constantsc11=28.15±0.5,c12=3.7±0.5 andc44=2.85±0.1 1010 dyn/cm2. A comparison with first sound elastic constants taken from ultrasonic measurements yields significant differences between the high and low frequency elastic constantsc11 andc″=(c1…
Inelastic neutron scattering by coupled rotational and translational modes in KCN
The TA [100] phonon branch of the molecular crystal KCN was studied by inelastic neutron scattering in the cubic phase. In addition the distribution of the quasielastic scattered neutrons was investigated. The results are analysed by assuming a coupling of the phonon modes to the rotational degrees of freedom of the CN-dumb-bells which are regarded as a system of interacting quadrupoles. A good description of the present results and also of the existing ultrasonic and Brillouin data is achieved by a simple model which uses a single collective rotational mode of finite excitation energy and line width.
Coupled rotational and translational modes in the mixed molecular crystal KBr1?x (CN) x
TheE g andT 2g acoustic phonon modes of the molecular crystals KBr0.96(CN)0.04 and KBr0.86(CN)0.14 have been investigated by inelastic neutron scattering at 6, 90 and 300 K. Clear resonances due to mode-mode coupling to molecular excitations were observed. In complementary ultrasonic experiments the elastic constants were found to pass through minima as a function of temperature. The results were quantitavely explained by a model which assumes simple forms of the molecular excitation spectrum. An alternative interpretation, though being only qualitative, postulates a freezing of the CN molecules into a glass-like phase.