0000000000385039
AUTHOR
F. Fegel
Circular dichroism in x-ray photoemission from core levels of nonmagnetic species
Circular dichroism in the angular distribution of photoelectrons (CDAD) has been observed in core-level photoemission from spherically symmetric initial states of nonmagnetic species utilizing circularly polarized soft-x-ray radiation from BESSY. Up to now, CDAD was predicted and observed only for aligned initial states. The data for oriented CO molecules prove that circular x-ray dichroism in photoemission from core levels is a general phenomenon that is not restricted to ferromagnets. High asymmetries of 50% suggest future applications as an effective circular x-ray analyzer.
Orientation and substrate interaction of adsorbed CO and NO molecules probed by circular dichroism in the angular distribution of photoelectrons.
The sensitivity and utility of circular dichroism in the angular distribution of photoelectrons (CDAD) as a probe of molecular orientation is demonstrated for adsorbed CO and NO molecules. A comparison between measured CDAD spectra and calculated values for spatially oriented CO and NiCO clearly confirms the well-known perpendicular adsorption for CO on Ni(100), whereas for CO adsorbed on Fe(100) a tilted adsorption geometry was found. For NO/Ni(100) and for NO on the oxygen-preadsorbed Ni(100) surface, an average tilt angle of α=40±10° was observed. In the case of the oxygen-preadsorbed Ni(100) surface, a higher fraction of NO molecules was found to be in a tilted orientation than on the c…