0000000000385140
AUTHOR
Cirino Vasi
showing 5 related works from this author
Non-Invasive Investigation of Pigments of Wall Painting in S. Maria Delle Palate di Tusa (Messina, Italy)
2019
The characterization of materials used in the archaeological field needs an experimental approach in order to avoid the destruction or perturbation of artworks. In order to afford this purpose, a multi-analytical spectroscopic approach is regularly used. We combined non-invasive analysis by using handheld spectroscopic instrumentations (mainly XRF and Raman spectrometers) in order to characterize the wall painting preserved in the church of S. Maria delle Palate at Halaesa Arconidea archeological site (Tusa, Messina, Italy). The aim of the work is the characterization of the nature of pigments used for the realization of the wall painting. The wall painting, probably representing St. Franci…
Hydrogen bond studies on n-pentanol and 2-methyl-2-butanol by Raman spectroscopy
1986
Polarized Raman spectra of n-pentanol and its isomer 2-methyl-2-butanol are obtained in the liquid phase near the melting points and at superheated temperatures. The measurements are performed in the intramolecular O-H stretching region. Our analysis of the Raman data provides an interpretation of the spectral features in terms of symmetric O-H bands, originated by various degrees of intermolecular coupling, for which mechanism is different for the two isomers. Temperature dependence of the spectra is also discussed in terms of available structural and dynamical models for these H-bonded liquids.
Correlation spectroscopy in molten and supercooled antimony trichloride.
1990
Correlation spectroscopy measurements performed on molten and supercooled antimony trichloride with the homodyne technique show correlation functions that have a nonexponential behavior. Two well-defined distributions of correlation times can be observed in different temporal regions. This behavior is discussed in terms of a structural relaxation of clusters dynamically formed by intermolecular and interchain bonds. The Arrhenius plot of these correlation times shows a linear behavior with the same activation energy for both. In contrast, the activation energy of shear viscosity has a different value, showing that the processes determining the temperature behavior of \ensuremath{\tau} and $…
A multivariate statistical approach of X-ray fluorescence characterization of a large collection of reverse glass paintings
2019
We present an X-ray fluorescence spectroscopy (XRF) study combined with a multivariate approach that allow to detect compositional differences and similarities among the glass supports of a large set of reverse glass paintings belonging to the collection of the Mistretta museum. Reverse painting on glass is an old decorative technique used since the Roman time consisting in applying a cold paint layer on the reverse side of a glass support. The collection shows a large spreading of provenience and dating of the items. In consideration of the current classification solely based on stylistic criteria, we applied a multivariate analysis on the XRF measurements data set to find a more objective…
A combination of portable non-invasive techniques to study on reverse glass paintings at Mistretta museum
2019
Abstract Reverse painting on glass is an old decorative technique used since the Roman time consisting in applying a cold paint layer on the reverse side. The Sicilian Regional Museum of forestry and pastoral traditions in Mistretta (Messina, Italy) houses the largest collection of reverse glass paintings in Italy with a total of 195 artworks. The artworks are attributed to the different Italian geographic area from north to south Italy. A combination of non-invasive analysis by using complementary portable spectroscopic instrumentations (mainly XRF and Raman Spectrometers) was applied on some selection of reverse glass paintings. The goal of the work is the characterization of the nature o…