The Formation of Glycerol Oligomers with Two New Types of End Groups in the Presence of a Homogeneous Alkaline Catalyst
The purpose of this work was to synthesize and characterize oligoglycerols with the chains of more than four repeating units. Those oligoglycerols may have some interesting applications, among others, as polyoxyalkylation starters. The glycerol oligomerization process was carried out during 12 h, at 230 °
The roles for a Lewis base and MgCl2 in third-generation Ziegler-Natta catalysts
Activity of a titanium catalyst supported on a bimetallic magnesium-aluminium system, involving a Lewis base [MgCl2(THF) 2 /Al(C 2 H 5 ) 2 Cl], was studied in ethylene polymerization, and the effect of the catalyst composition on the properties of the final polymer produced was investigated. Analysis and discussion of the findings covering also some part of the kinetic study, resulted in defining the roles for MgCl 2 and a Lewis base in the third-generation Ziegler-Natta catalysts. MgCl 2 forms a bimetallic complex with an organoaluminium compound, which involves also a Lewis base. Its reaction with TiCl 4 yields a very active catalyst wherein the Mg: Ti molar ratio is close to 1. This mean…
The role of nanoparticles in decreased washout of underwater concrete
Abstract The paper presents research results of the influence of SiO2 nanoparticles on the washout of underwater concrete and hardened concrete. Based on infrared spectroscopy (FTIR) and thermogravimetric (TGA) analyses of the applied anti-washout admixture (AWA), its chemical structure was determined. A beneficial effect of SiO2 nanoparticles on the reduction of the mix washout was demonstrated and the most probable reason for that phenomenon was given, taking into account the AWA chemical structure and its behaviour in the concrete mix environment. It was found that a dosing method of AWA and nanoparticles to the concrete influenced the washout.
Star poly(2-ethyl-2-oxazoline)s-synthesis and thermosensitivity
A series of star-shaped poly(2-ethyl-2-oxazoline)s was prepared by cationic polymerization. The polymerization was initiated by dipentaerythrityl hexakis(4-nitrobenzene sulfonate) and a tosylated hyperbranched polymer of glycidol. The polymerization proceeded in a controlled manner. The star structure of the products was determined by nuclear magnetic resonance. The molar mass distributions that were measured by gel permeation chromatography with multiangle laser light scattering were narrow, and the experimental values of the molar masses were close to those predicted. The very compact structure of the polymers obtained (compared with the linear counterparts) confirmed the star formation. …