0000000000390614

AUTHOR

Matthias Schrade

0000-0002-9501-6536

showing 3 related works from this author

Fabrication of a Silicide Thermoelectric Module Employing Fractional Factorial Design Principles

2021

AbstractThermoelectric modules can be used in waste heat harvesting, sensing, and cooling applications. Here, we report on the fabrication and performance of a four-leg module based on abundant silicide materials. While previously optimized Mg2Si0.3Sn0.675Bi0.025 is used as the n-type leg, we employ a fractional factorial design based on the Taguchi methods mapping out a four-dimensional parameter space among Mnx-εMoεSi1.75−δGeδ higher manganese silicide compositions for the p-type material. The module is assembled using a scalable fabrication process, using a Cu metallization layer and a Pb-based soldering paste. The maximum power output density of 53 μW cm–2 is achieved at a hot-side temp…

fractional factorial designFabricationMaterials sciencesilicide thermoelectric modulebusiness.industryContact resistanceFractional factorial designCondensed Matter PhysicsThermoelectric materialsElectronic Optical and Magnetic MaterialsTaguchi methodschemistry.chemical_compoundThermoelectric generatorchemistryThermoelectric effectSilicideMaterials ChemistryOptoelectronicsElectrical and Electronic Engineeringbusiness
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Tetragonal tungsten bronzes Nb8−xW9+xO47−δ: optimization strategies and transport properties of a new n-type thermoelectric oxide

2015

Engineering of nanoscaled structures may help controlling the electrical and thermal transport in solids, in particular for thermoelectric applications that require the combination of low thermal conductivity and low electrical resistivity. The tetragonal tungsten bronzes Nb8−xW9+xO47 (TTB) allow a continuous variation of the charge carrier concentration while fulfilling at the same time the concept of a “phonon-glass electron-crystal” through a layered nanostructure defined by intrinsic crystallographic shear planes. The thermoelectric properties of the tetragonal tungsten bronzes Nb8−xW9+xO47−δ (0 < x < 2) were studied in the temperature range from 373 to 973 K. Structural defects and the…

n-type thermoelectric oxideMaterials scienceProcess Chemistry and TechnologyAnalytical chemistryMineralogychemistry.chemical_elementAtmospheric temperature rangeTungstenThermogravimetryTetragonal crystal systemThermal conductivitychemistrytransport propertiesMechanics of MaterialsElectrical resistivity and conductivitySeebeck coefficientThermoelectric effectGeneral Materials ScienceElectrical and Electronic Engineering
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Thermal stability and enhanced thermoelectric properties of the tetragonal tungsten bronzes Nb8-xW9+xO47 (0 &lt;x &lt;5)

2017

Thermoelectric materials are believed to play a fundamental role in the energy field over the next years thanks to their ability of directly converting heat into usable electric energy. To increase their integration in the commercial markets, improvements of the efficiencies are needed. At the same time, cheap and non-toxic materials are required along with easily upscalable production cycles. Compounds of the tetragonal tungsten bronze (TTB) series Nb8-xW9+xO47 fulfill all these requirements and are promising materials. Their adaptive structure ensures glass-like values of the thermal conductivity, and the substitution on the cation side allows a controlled manipulation of the electronic p…

Materials scienceEQUILIBRIATITANIUM-OXYGEN SYSTEMCRYSTALLOGRAPHIC SHEARchemistry.chemical_elementNanotechnology02 engineering and technologyTemperature cyclingThermal treatmentTungsten010402 general chemistry01 natural sciencesTHERMOPOWERPHYSICSTetragonal crystal systemThermal conductivityThermoelectric effectMETAL-OXIDESGeneral Materials ScienceThermal stabilityCRYSTAL-STRUCTURESRenewable Energy Sustainability and the EnvironmentMOLYBDENUMGeneral ChemistryPERFORMANCE021001 nanoscience & nanotechnologyThermoelectric materials0104 chemical sciencesChemical engineeringchemistry0210 nano-technologyPB
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