0000000000400790

AUTHOR

Constantin G. Daniliuc

0000-0002-6709-3673

showing 53 related works from this author

Insertion Reactions of Neutral Phosphidozirconocene Complexes as a Convenient Entry into Frustrated Lewis Pair Territory

2016

International audience; Neutral phosphidozirconocene complexes [Cp2Zr(PR2)Me] (Cp=cyclopentadienyl; 1a: R=cyclohexyl (Cy); 1b: R=mesityl (Mes); 1c: R=tBu) undergo insertion into the Zr-P bond by non-enolisable carbonyl building blocks (O=CRR), such as benzophenone, aldehydes, paraformaldehyde or CO2, to give [Cp2Zr(OCRRPR2)Me] (3-7). Depending on the steric bulk around P, complexes 3-7 react with B(C6F5)(3) to give O-bridged cationic zirconocene dimers that display typical frustrated Lewis pair (FLP)/ambiphilic ligand behaviour. Thus, the reaction of {[Cp2Zr(-OCHPhPCy2)][MeB(C6F5)(3)]}(2) (10a) with chalcone results in 1,4 addition of the Zr+/P FLP, whereas the reaction of {[Cp2Zr(-OCHFcPCy…

Steric effectsChalconeStereochemistryzirconiumc-h activation010402 general chemistry01 natural sciencesMedicinal chemistry[ CHIM ] Chemical SciencesCatalysisFrustrated Lewis pairinsertionchemistry.chemical_compoundCyclopentadienyl complexx-ray structuresphosphinidene complexesBenzophenone[CHIM]Chemical SciencesParaformaldehydezr-p bondzirconocene-phosphido complexesmolecular-structure010405 organic chemistryLigandphosphidesOrganic ChemistryCationic polymerizationcrystal-structureGeneral Chemistry0104 chemical sciencesfunctionalized ligandsbis(trimethylsilyl)phosphido complexeschemistryfrustrated Lewis pairsphosphinoaryloxide complexesambiphilic ligands
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Phosphido- and Amidozirconocene Cation-Based Frustrated Lewis Pair Chemistry

2015

Methyl abstraction from neutral [Cp2ZrMe(ERR')] complexes 1 (E = N, P; R, R' = alkyl, aryl) with either B(C6F5)3 or [Ph3C][B(C6F5)4] results in the formation of [Cp2Zr(ERR')][X] complexes 2 (X(-) = MeB(C6F5)3(-), B(C6F5)4(-)). The X-ray structure of amido complexes [Cp2Zr(NPh2)][MeB(C6F5)3] (2d) and [Cp2Zr(N(t)BuAr)][B(C6F5)4] (2e', Ar = 3,5-C6H3(CH3)2) is reported, showing a sterically dependent Zr/N-π interaction. Complexes 2 catalyze the hydrogenation of electron-rich olefins and alkynes under mild conditions (room temperature, 1.5 bar H2). Complex 2e binds CO2, giving [Cp2Zr(CO2)(N(t)BuAr)]2[MeB(C6F5)3]2 (3e). Amido complex 2d reacts with benzaldehyde yielding [Cp2Zr(OCH2Ph)((OC)PhNPh2)…

chemistry.chemical_classificationSteric effectsStereochemistryArylGeneral ChemistryBiochemistryMedicinal chemistryCatalysisFrustrated Lewis pairBenzaldehydechemistry.chemical_compoundColloid and Surface ChemistrychemistryDiphenylacetyleneAlkylJournal of the American Chemical Society
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Mesogens with Aggregation-Induced Emission Formed by Hydrogen Bonding

2019

In this contribution, we report a supramolecular approach toward mesogens showing aggregation-induced emission (AIE). AIE-active aromatic thioethers, acting as hydrogen-bond donors, were combined with alkoxystilbazoles as hydrogen-bond acceptors. Upon self-assembly, hydrogen-bonded complexes with monotropic liquid crystalline behavior were obtained. In addition, it was found that the introduction of a chiral citronellyl side chain leads to drastic bathochromic shift of the emission, which was not observed for linear alkyl chains. The mesomorphic behavior, as well as the photophysical properties as a solid and in the mesophase of the liquid crystalline assemblies, were studied in detail.

Materials scienceHydrogen bondGeneral Chemical EngineeringChemieBiomedical EngineeringSupramolecular chemistryGeneral Materials ScienceSettore CHIM/07 - Fondamenti Chimici Delle TecnologieAggregation-induced emissionPhotochemistryAggregation-Induced-Emission Hydrogen Bonding Liquid Crystals Supramolecular Chemistry Computational ChemistryACS Materials Letters
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Improving the mesomorphic behaviour of supramolecular liquid crystals by resonance-assisted hydrogen bonding

2019

A systematic structure-property relationship study on hydrogen-bonded liquid crystals was performed, revealing the impact of resonance-assisted hydrogen bonds (RAHBs) on the self-assembling behavior of the supramolecular architecture. The creation of a six-membered intramolecular hydrogen-bonded ring acts as a counterpart to the self-organization between hydrogen bond donators and acceptors and determines thus the suprastructure. Variation of the hydrogen-bonding pattern allowed us to significantly improve the temperature range of the reported liquid crystalline assemblies.

Materials scienceLiquid crystallineHydrogen bondChemieSupramolecular chemistry02 engineering and technologyGeneral ChemistryAtmospheric temperature range010402 general chemistry021001 nanoscience & nanotechnologyRing (chemistry)Resonance (chemistry)01 natural sciences0104 chemical sciencesCrystallographyLiquid Crystals Hydrogen Bonding Structure-Property Supramolecular Chemistry intramolecularLiquid crystalIntramolecular forceMaterials ChemistrySettore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologyJournal of Materials Chemistry C
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Naturally occurring polyphenols as building blocks for supramolecular liquid crystals – substitution pattern dominates mesomorphism

2021

A modular supramolecular approach towards hydrogen-bonded liquid crystalline assemblies based on naturally occurring polyphenols is reported. The combination of experimental observations, crystallographic studies and semi-empirical analyses of the assemblies provides insight into the structure–property relationships of these materials. Here a direct correlation of the number of donor OH-groups as well as their orientation with the mesomorphic behavior is reported. We discovered that the number and orientation of the OH-groups have a stronger influence on the mesomorphic behavior of the supramolecular assemblies than the connectivity (e.g. stilbenoid or chalconoid) of the hydrogen bond donor…

ChemistryHydrogen bondLiquid crystallineProcess Chemistry and TechnologyChemieBiomedical EngineeringSupramolecular chemistryEnergy Engineering and Power Technology02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesIndustrial and Manufacturing Engineering0104 chemical sciencesCrystallographyChemistry (miscellaneous)Liquid crystalSupramolecular Chemistry Liquid Crystals Crystal Engineering Hydrogen BondingMaterials ChemistryChemical Engineering (miscellaneous)Settore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologyMolecular Systems Design & Engineering
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ChemInform Abstract: Phosphido- and Amidozirconocene Cation-Based Frustrated Lewis Pair Chemistry.

2016

Methyl abstraction from neutral [Cp2ZrMe(ERR′)] complexes 1 (E = N, P; R, R′ = alkyl, aryl) with either B(C6F5)3 or [Ph3C][B(C6F5)4] results in the formation of [Cp2Zr(ERR′)][X] complexes 2 (X– = MeB(C6F5)3–, B(C6F5)4–). The X-ray structure of amido complexes [Cp2Zr(NPh2)][MeB(C6F5)3] (2d) and [Cp2Zr(NtBuAr)][B(C6F5)4] (2e′, Ar = 3,5-C6H3(CH3)2) is reported, showing a sterically dependent Zr/N−π interaction. Complexes 2 catalyze the hydrogenation of electron-rich olefins and alkynes under mild conditions (room temperature, 1.5 bar H2). Complex 2e binds CO2, giving [Cp2Zr(CO2)(NtBuAr)]2[MeB(C6F5)3]2 (3e). Amido complex 2d reacts with benzaldehyde yielding [Cp2Zr(OCH2Ph)((OC)PhNPh2)][MeB(C6F5…

chemistry.chemical_classificationBenzaldehydeSteric effectschemistry.chemical_compoundchemistryArylGeneral MedicineDiphenylacetyleneMedicinal chemistryAlkylFrustrated Lewis pairChemInform
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Direct P-functionalization of azobenzene by a cationic phosphidozirconocene complex.

2016

International audience; We report that the cationic phosphidozirconocene complex [(eta(5)-C5H5)(2)Zr(PCy2)][CH3B(C6F5)(3)] (II) reacts with azobenzene, resulting in the expedient formation of Zr complex (2) bound to a tridentate PNN ligand. This reaction proceeds by a mechanism of cooperative nucleophilic substitution of hydrogen. The intermediate sigma(H) adduct (1) has been characterized by NMR spectroscopy.

ortho-acylationHydrogenaromatic azo-compoundschemistry.chemical_element[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistryBioinformatics01 natural sciences[ CHIM ] Chemical SciencesAdductalcoholsInorganic Chemistrychemistry.chemical_compoundc-h functionalizationPolymer chemistryNucleophilic substitution[CHIM]Chemical Sciences010405 organic chemistryChemistryLigandCationic polymerizationcinnolinium salts[ CHIM.INOR ] Chemical Sciences/Inorganic chemistryNuclear magnetic resonance spectroscopy0104 chemical sciences3. Good healthAzobenzeneazoxybenzenesalpha-oxocarboxylic acidsazoareneshydrogennucleophilic-substitutionSurface modificationDalton transactions (Cambridge, England : 2003)
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Synthetic Endeavors toward Titanium Based Frustrated Lewis Pairs with Controlled Electronic and Steric Properties

2015

A new family of cationic Ti complexes 4′ with a pendant phosphine of general formula [CpCpPTiOAr][BPh4] (Cp = η5-C5H5; CpP = η5-C5H4(CMe2)PR2) has been prepared in four steps from 6,6-dimethylfulvene. These complexes were designed to behave as Ti based frustrated Lewis pairs (FLPs). The key synthetic step is a reduction–oxidation sequence from [CpCpPTiClOAr] complexes 3 using lithium phosphide salts as the reductants and ferricinium tetraphenylborate as the oxidant. Four complexes have been structurally characterized by X-ray diffraction and show elongated Ti–P bonds, above 2.60 A. One complex (4b′: OAr = 2,6-Me2C6H3; PR2 = PCy2) reacted with benzaldehyde to form a typical FLP activation pr…

Steric effectsTetraphenylboratePhosphideStereochemistryOrganic ChemistryCationic polymerizationFrustrated Lewis pairInorganic ChemistryBenzaldehydechemistry.chemical_compoundchemistryPolymer chemistryPhosphoniumPhysical and Theoretical ChemistryPhosphineOrganometallics
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Structure-property relationships in aromatic thioethers featuring aggregation-induced emission : Solid-state structures and theoretical analysis

2019

We describe in this paper a structure–property relationship study of aromatic thioethers with aggregation-induced emission (AIE) properties. We combine a structural analysis based on geometrical consideration with an in-depth analysis of the crystalline packing supported by quantum mechanical calculations. Our results allow us to correlate the enhanced fluorescence quantum yields with the significant increase of C–H⋯π and the decrease of π⋯π interactions in the solid state – a result which supports the well-accepted AIE mechanism quantitatively.

Materials scienceSolid-stateChemieStructure property02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnologyCondensed Matter Physics01 natural sciencesFluorescence0104 chemical sciencesChemical physicsGeneral Materials ScienceSettore CHIM/07 - Fondamenti Chimici Delle TecnologieAggregation-induced emission0210 nano-technologyAggregation-Induced-Emission Packing Computational Chemistry FluorescenceQuantum
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Desymmetrization of Prochiral Cyclobutanones via Nitrogen Insertion: A Concise Route to Chiral γ‐Lactams

2021

Abstract Asymmetric access to γ‐lactams is achieved via a cyclobutanone ring expansion using widely available (1S,2R)‐1‐amino‐2‐indanol for chiral induction. Mechanistic analysis of the key N,O‐ketal rearrangement reveals a Curtin–Hammett scenario, which enables a downstream stereoinduction (up to 88:12 dr) and is corroborated by spectroscopic, crystallographic, and computational studies. In combination with an easy deprotection protocol, this operationally simple sequence allows the synthesis of a range of optically pure γ‐lactams, including those bearing all‐carbon quaternary stereocenters. In addition, the formal synthesis of drug molecules baclofen, brivaracetam, and pregabalin further …

γ-lactamsChiral auxiliary010405 organic chemistryChemistryasymmetric synthesisEnantioselective synthesisCyclobutanoneGeneral Chemistry010402 general chemistryRing (chemistry)01 natural sciencesCombinatorial chemistryDesymmetrizationCatalysis0104 chemical sciencesStereocenterdesymmetrizationFormal synthesischemistry.chemical_compoundMoleculecyclobutanoneResearch ArticlesResearch ArticleAsymmetric Synthesis | Hot PaperAngewandte Chemie International Edition
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Desymmetrisierung von prochiralen Cyclobutanonen via Stickstoffinsertion: Ein einfacher Zugang zu chiralen γ‐Lactamen

2021

ChemistryGeneral MedicineAngewandte Chemie
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CCDC 1421130: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(di-t-butylphospheanyl)-methyl-zirconiumExperimental 3D Coordinates
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CCDC 1424182: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Chem.-Eur.J.|22|4285|doi:10.1002/chem.201504792

Space GroupCrystallographyCrystal System((Dicyclohexylphosphino)methanolato)-bis(eta5-cyclopentadienyl)-methyl-zirconiumCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1894901: Experimental Crystal Structure Determination

2019

Related Article: Marco Saccone, Steffen Riebe, Jacqueline Stelzer, Christoph Wölper, Constantin G. Daniliuc, Jens Voskuhl, Michael Giese|2019|CrystEngComm|21|3097|doi:10.1039/C9CE00444K

Space GroupCrystallographyCrystal SystemCrystal Structure46-bis{[2-(octyloxy)phenyl]sulfanyl}benzene-13-dicarbonitrileCell ParametersExperimental 3D Coordinates
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CCDC 1053357: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallographyCrystal SystemCrystal Structure(1-((2-(bis(2-methylphenyl)phosphino)-1-methyl)ethyl)cyclopentadienyl)-(cyclopentadienyl)-(26-dimethylphenolato)-titanium tetraphenylborateCell ParametersExperimental 3D Coordinates
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CCDC 1424183: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Chem.-Eur.J.|22|4285|doi:10.1002/chem.201504792

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu2-(Dicyclohexylphosphino)methanolato)-tetrakis(eta5-cyclopentadienyl)-di-zirconium tetrakis(pentafluorophenyl)borate dichloromethane solvateExperimental 3D Coordinates
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CCDC 1893331: Experimental Crystal Structure Determination

2019

Related Article: Marco Saccone, Steffen Riebe, Jacqueline Stelzer, Christoph Wölper, Constantin G. Daniliuc, Jens Voskuhl, Michael Giese|2019|CrystEngComm|21|3097|doi:10.1039/C9CE00444K

Space GroupCrystallography46-bis{[4-(nonyloxy)phenyl]sulfanyl}benzene-13-dicarbonitrileCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1424177: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Chem.-Eur.J.|22|4285|doi:10.1002/chem.201504792

Space GroupCrystallographybis(eta5-Cyclopentadienyl)-((dimesitylphosphino)(phenyl)methanolato)-methyl-zirconiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1895359: Experimental Crystal Structure Determination

2019

Related Article: Marco Saccone, Steffen Riebe, Jacqueline Stelzer, Christoph Wölper, Constantin G. Daniliuc, Jens Voskuhl, Michael Giese|2019|CrystEngComm|21|3097|doi:10.1039/C9CE00444K

Space GroupCrystallographyCrystal System25-bis{[3-(octyloxy)phenyl]sulfanyl}benzene-14-dicarbonitrileCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1052598: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallography(eta5-cyclopentadienyl)-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(4-methoxyphenolato)-titanium tetraphenylborateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421134: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(tert-butyl(35-dimethylphenyl)amido)-zirconium tetrakis(pentafluorophenyl)borate unknown solvateExperimental 3D Coordinates
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CCDC 1052596: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

(eta5-cyclopentadienyl)-phenolato-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-titanium tetraphenylborateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1895424: Experimental Crystal Structure Determination

2019

Related Article: Marco Saccone, Steffen Riebe, Jacqueline Stelzer, Christoph Wölper, Constantin G. Daniliuc, Jens Voskuhl, Michael Giese|2019|CrystEngComm|21|3097|doi:10.1039/C9CE00444K

Space GroupCrystallographyCrystal System46-bis[4-(octyloxy)phenoxy]benzene-13-dicarbonitrileCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421135: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-t-butyl(35-dimethylphenyl)carbamato)-tetrakis(eta5-cyclopentadienyl)-di-zirconium bis(methyl(tris(pentafluorophenyl))borate) unknown solvateExperimental 3D Coordinates
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CCDC 1052597: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(eta5-cyclopentadienyl)-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(26-dimethylphenolato)-titanium tetraphenylborate dichloromethane solvateExperimental 3D Coordinates
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CCDC 1052593: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(eta5-cyclopentadienyl)-phenolato-chloro-titaniumExperimental 3D Coordinates
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CCDC 1942435: Experimental Crystal Structure Determination

2021

Related Article: Jan Balszuweit, Meik Blanke, Marco Saccone, Markus Mezger, Constantin G. Daniliuc, Christoph Wölper, Michael Giese, Jens Voskuhl|2021|MSDE|6|390|doi:10.1039/D0ME00171F

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-[2-(35-dihydroxyphenyl)ethenyl]benzene-12-diol tris(4-{2-[4-(octyloxy)phenyl]ethenyl}pyridine)Experimental 3D Coordinates
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CCDC 1421138: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(3-(dicyclohexyl[12-diphenylethenyl]phosphonio)-13-diphenylprop-1-en-1-olato)-zirconium tetrakis(35-bis(trifluoromethyl)phenyl)borate unknown solvateExperimental 3D Coordinates
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CCDC 1053358: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

(cyclopentadienyl)-([dicyclohexyl(2-cyclopentadienylpropan-2-yl)phosphaniumyl](phenyl)methoxy)-(26-dimethylphenolato)-titanium tetraphenylborate tetrahydrofuran solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2051971: Experimental Crystal Structure Determination

2021

Related Article: Jan Sietmann, Mike Ong, Christian Mück-Lichtenfeld, Constantin G. Daniliuc, Johannes M. Wiest|2021|Angew.Chem.,Int.Ed.|60|9719|doi:10.1002/anie.202100642

Space GroupCrystallographyCrystal SystemCrystal Structure1-(2-hydroxy-23-dihydro-1H-inden-1-yl)-4-phenylpyrrolidin-2-oneCell ParametersExperimental 3D Coordinates
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CCDC 1421133: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographyCrystal Systembis(eta5-cyclopentadienyl)-(diphenylamido)-zirconium methyl(tris(pentafluorophenyl))borateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1945777: Experimental Crystal Structure Determination

2021

Related Article: Jan Balszuweit, Meik Blanke, Marco Saccone, Markus Mezger, Constantin G. Daniliuc, Christoph Wölper, Michael Giese, Jens Voskuhl|2021|MSDE|6|390|doi:10.1039/D0ME00171F

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters4-[2-(35-dihydroxyphenyl)ethenyl]benzene-12-diol tris(4-{[4-(octyloxy)phenyl]diazenyl}pyridine)Experimental 3D Coordinates
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CCDC 1424181: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Chem.-Eur.J.|22|4285|doi:10.1002/chem.201504792

Space GroupCrystallography(Dicyclohexylphosphinecarboxylato)-bis(eta5-cyclopentadienyl)-methyl-zirconiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1052592: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

(eta5-cyclopentadienyl)-(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-dimethyl-titaniumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421131: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographybis(eta5-cyclopentadienyl)-diphenylamido-methyl-zirconiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1052595: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallography(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(4-methoxyphenolato)-(eta5-cyclopentadienyl)-chloro-titaniumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1938656: Experimental Crystal Structure Determination

2021

Related Article: Marco Saccone, Meik Blanke, Constantin G. Daniliuc, Heikki Rekola, Jacqueline Stelzer, Arri Priimagi, Jens Voskuhl, Michael Giese|2019|ACS Materials Lett.|1|589|doi:10.1021/acsmaterialslett.9b00371

46-bis[(3-hydroxyphenyl)sulfanyl]benzene-13-dicarbonitrile bis(4-{2-[4-(octyloxy)phenyl]ethenyl}pyridine)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1052594: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Philippe Richard, Cédric Balan, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker, Pierre Le Gendre|2015|Organometallics|34|2000|doi:10.1021/acs.organomet.5b00250

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-[2-(dicyclohexylphosphanyl)propan-2-yl]cyclopentadienyl)-(eta5-cyclopentadienyl)-chloro-(26-dimethylphenolato)-titaniumExperimental 3D Coordinates
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CCDC 2051973: Experimental Crystal Structure Determination

2021

Related Article: Jan Sietmann, Mike Ong, Christian Mück-Lichtenfeld, Constantin G. Daniliuc, Johannes M. Wiest|2021|Angew.Chem.,Int.Ed.|60|9719|doi:10.1002/anie.202100642

3-phenyl-3'3'a8'8'a-tetrahydrospiro[cyclobutane-12'-indeno[12-d][13]oxazole]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421128: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

bis(eta5-cyclopentadienyl)-dicyclohexylphosphanyl-methyl-zirconiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421129: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

bis(eta5-cyclopentadienyl)-dimesitylphosphanyl-methyl-zirconiumSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421132: Experimental Crystal Structure Determination

2015

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, and Gerhard Erker|2015|J.Am.Chem.Soc.|137|10796|doi:10.1021/jacs.5b06551

Space GroupCrystallographyCrystal Systembis(eta5-cyclopentadienyl)-(tert-butyl(35-dimethylphenyl)amido)-methyl-zirconiumCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1424178: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Birgit Wibbeling, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Chem.-Eur.J.|22|4285|doi:10.1002/chem.201504792

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters((Di-t-butylphosphino)(phenyl)methanolato)-bis(eta5-cyclopentadienyl)-methyl-zirconiumExperimental 3D Coordinates
researchProduct

CCDC 1440373: Experimental Crystal Structure Determination

2016

Related Article: Adrien T. Normand, Constantin G. Daniliuc, Gerald Kehr, Pierre Le Gendre, Gerhard Erker|2016|Dalton Trans.|45|3711|doi:10.1039/C6DT00416D

bis(cyclopentadienyl)-(1-(2-(dicyclohexylphosphanyl)phenyl)-2-phenyldiazanediido)-zirconium(iv)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2051972: Experimental Crystal Structure Determination

2021

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Space GroupCrystallography1-(2-hydroxy-23-dihydro-1H-inden-1-yl)-4-methyl-4-phenylpyrrolidin-2-oneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1424179: Experimental Crystal Structure Determination

2016

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Space GroupCrystallography((Dicyclohexylphosphino)(diphenyl)methanolato)-bis(eta5-cyclopentadienyl)-methyl-zirconium n-pentane solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1895360: Experimental Crystal Structure Determination

2019

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters25-bis{[2-(octyloxy)phenyl]sulfanyl}benzene-14-dicarbonitrileExperimental 3D Coordinates
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CCDC 1440372: Experimental Crystal Structure Determination

2016

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bis(cyclopentadienyl)-(1-(2-(dicyclohexylphosphanyl)phenyl)-2-phenylhydrazin-1-ido)-zirconium(iv) tetrakis(pentafluorophenyl)borateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2051970: Experimental Crystal Structure Determination

2021

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CCDC 1421136: Experimental Crystal Structure Determination

2015

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(eta5-cyclopentadienyl)-(NN-diphenylbenzamide)-(phenylmethanolato)-zirconium tetrakis(35-bis(trifluoromethyl)phenyl)borateExperimental 3D Coordinates
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CCDC 1424180: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal SystemCrystal Structure((Di-t-butylphosphino)(diphenyl)methanolato)-bis(eta5-cyclopentadienyl)-methyl-zirconiumCell ParametersExperimental 3D Coordinates
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CCDC 1424184: Experimental Crystal Structure Determination

2016

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Space GroupCrystallographyCrystal System(mu2-Chloro)-(mu2-(dicyclohexylphosphino)ferrocenylmethanolato-OP)-(eta3-allyl)-bis(eta5-cyclopentadienyl)-palladium-zirconium tetrakis(pentafluorophenyl)borateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1421137: Experimental Crystal Structure Determination

2015

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