0000000000403868

AUTHOR

Stefan Dolezel

showing 2 related works from this author

Strategy for good dispersion of well-defined tetrapods in semiconducting polymer matrices.

2014

The morphology or dispersion control in inorganic/organic hybrid systems is studied, which consist of monodisperse CdSe tetrapods (TPs) with grafted semiconducting block copolymers with excess polymers of the same type. Tetrapod arm-length and amount of polymer loading are varied in order to find the ideal morphology for hybrid solar cells. Additionally, polymers without anchor groups are mixed with the TPs to study the effect of such anchor groups on the hybrid morphology. A numerical model is developed and Monte Carlo simulations to study the basis of compatibility or dispersibility of TPs in polymer matrices are performed. The simulations show that bare TPs tend to form clusters in the m…

chemistry.chemical_classificationMaterials sciencePolymers and PlasticsPolymersOrganic ChemistryMonte Carlo methodDispersityPolymerHybrid solar cellMatrix (mathematics)chemistryMicroscopy Electron TransmissionSemiconductorsTransmission electron microscopyMaterials ChemistryCopolymerCadmium CompoundsComposite materialWell-definedSelenium CompoundsMonte Carlo MethodMacromolecular rapid communications
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On ripples and rafts: Curvature induced nanoscale structures in lipid membranes

2014

We develop an elastic theory that predicts the spontaneous formation of nanoscale structures in lipid bilayers which locally phase separate between two phases with different spontaneous monolayer curvature. The theory rationalizes in a unified manner the observation of a variety of nanoscale structures in lipid membranes: Rippled states in one-component membranes, lipid rafts in multicomponent membranes. Furthermore, we report on recent observations of rippled states and rafts in simulations of a simple coarse-grained model for lipid bilayers, which are compatible with experimental observations and with our elastic model.

Physics::Biological PhysicsHistoryMaterials scienceNanotechnologyCurvatureQuantitative Biology::Cell BehaviorComputer Science ApplicationsEducationCondensed Matter::Soft Condensed MatterQuantitative Biology::Subcellular ProcessesMembranePhase (matter)MonolayerBiophysicslipids (amino acids peptides and proteins)Lipid bilayer phase behaviorLipid bilayerNanoscopic scaleLipid raftJournal of Physics: Conference Series
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