0000000000409576
AUTHOR
Adnen Mlayah
Acousto-Plasmonic Hot Spots: Driving Enhanced Raman Scattering in Metallic Nanoparticles
We study theoretically and experimentally the coupling of acoustic vibrations (phonons) and surface plasmons in metallic nano-objects. The modulation of the surface charge density allows for the interpretation of experimental Raman-Brillouin spectra in silver nanorods.
Number of observable features in the acoustic-Raman spectra of nanocrystals
Low-frequency Raman scattering spectra are presented for gold nanocrystals with diameters 3.5 and 13 nm. The frequencies of the Raman peaks but also their number are shown to vary with the nanocrystal size. These results are analyzed using both the continuous elastic medium approximation and an atomistic approach. We show that the number of atoms in the nanocrystal determines an upper limit of the number of observable Raman features. The frequency range in which the continuous elastic medium approximation is valid is defined by comparison with the calculations based on the atomistic approach.
Surface plasmons and vibrations of self-assembled silver nanocolumns
6 pags. ; 5 figs. 1 tab.
Surface enhanced Raman scattering of silver sensitized cobalt nanoparticles in metal–dielectric nanocomposites
We report the preparation of a new type of nanocomposite containing cobalt and silver nanoparticles organized in parallel layers with a well controlled separation. This arrangement allows the observation of an enhanced low-frequency Raman signal at the vibration frequency of cobalt nanoparticles excited through the surface plasmons of silver nanoparticles. Numerical simulations of the electric field confirm the emergence of hot spots when the separation between silver and cobalt nanoparticles is small enough. © IOP Publishing Ltd.
Acousto-plasmonic coupling in engineered metal nanocomposites
This work shows the production of self-assembled elongated nano-objects embedded in an oxide host oriented perpendicular to the substrate and their acousto-plasmonic dynamics. Electromagnetic “hot spots” are created that activate anomalous Raman vibrational modes.