0000000000409866
AUTHOR
Eduard Llobet
Gas sensing properties of multiwall carbon nanotubes decorated with rhodium nanoparticles
International audience; In the present work, multiwalled carbon nanotubes were decorated with rhodium nanoparticles using a colloidal solution in the post-discharge of an RF atmospheric plasma of argon (Ar) or argon/oxygen (Ar:O 2). The properties of these hybrid materials towards the room temperature detection of NO 2 , C 2 H 4 , CO, C 6 H 6 and moisture were investigated and discussed in view of compositional and morphological studies. It was found that the presence of oxygen in the plasma treatment is essential to significantly enhance the gas response of Rh-decorated multiwalled carbon nanotubes and to avoid response saturation even at low gas/vapor concentrations. These desirable effec…
Diamondoid Nanostructures as sp 3 ‐Carbon‐Based Gas Sensors
Diamondoids, sp3 -hybridized nanometer-sized diamond-like hydrocarbons (nanodiamonds), difunctionalized with hydroxy and primary phosphine oxide groups, enable the assembly of the first sp3 -C-based chemical sensors by vapor deposition. Both pristine nanodiamonds and palladium nanolayered composites can be used to detect toxic NO2 and NH3 gases. This carbon-based gas sensor technology allows reversible NO2 detection down to 50 ppb and NH3 detection at 25-100 ppm concentration with fast response and recovery processes at 100 °C. Reversible gas adsorption and detection is compatible with 50 % humidity conditions. Semiconducting p-type sensing properties are achieved from devices based on prim…
SPICE model for resistive gas and odour sensors
A generalised PSPICE model of resistive gas/odour sensors is presented. The model simulates the response of both polymeric and metal oxide devices, as well as an integrated resistive heater that is used to set the operating temperature. In both cases there was good agreement between the observed responses and the PSPICE simulated responses to rectangular pulses of gases. The PSPICE model is not only simpler and faster to use than analytical solutions, but also should permit the rapid prototyping of associated drive circuitry.
Electronic noses: a review of signal processing techniques
The field of electronic noses, electronic instruments capable of mimicking the human olfactory system, has developed rapidly in the past ten years. There are now at least 25 research groups working in this area and more than ten companies have developed commercial instruments, which are mainly employed in the food and cosmetics industries. Most of the work published to date, and commercial applications, relate to the use of well established static pattern analysis techniques, such as principal components analysis, discriminant function analysis, cluster analysis and multilayer perceptron based neural networks. The authors first review static techniques that have been applied to the steady-s…
CCDC 1875843: Experimental Crystal Structure Determination
Related Article: Oana Moncea, Juan Casanova-Chafer, Didier Poinsot, Lukas Ochmann, Clève D. Mboyi, Houssein O. Nasrallah, Eduard Llobet, Imen Makni, Molka El Atrous, Stéphane Brandès, Yoann Rousselin, Bruno Domenichini, Nicolas Nuns, Andrey A. Fokin, Peter R. Schreiner, Jean-Cyrille Hierso|2019|Angew.Chem.,Int.Ed.|58|9933|doi:10.1002/anie.201903089