0000000000409891

AUTHOR

Cédric Desplanches

0000-0001-8524-3690

showing 40 related works from this author

Two new supramolecular architectures of singly phenoxo-bridged copper(II) and doubly phenoxo-bridged manganese(II) complexes derived from an unusual …

2009

International audience; Two new coordination complexes {[(L)Cu2('-L)(NO3)(CH3OH)0.3(H2O)0.7]·NO3}[Cu(L)(NO3)(CH3OH)] (1) and [Mn2(-L)2(H2O)(1-N3)2(CH3OH)] (2) derived from (E)-N-(2-hydroxy-3-methoxybenzylidene)acetohydrazide [LH] have been synthesized. The new potentially tetradentate ONOO donor hydrazone ligand [LH] has shown considerable metal ion selective phenoxo bridging in 1 and 2. It has coordinated copper(II) ions in its tridentate as well as in tetradentate fashion whereas for manganese(II) ions it solely showed its tetradentate character. In 1 the two adjacent pentacoordinate copper(II) centers are connected by a rare single phenoxo linkage of the hydrazone ligand whereas 2 is a d…

StereochemistrySupramolecular chemistrychemistry.chemical_elementManganese010402 general chemistry01 natural sciencesHydrogen bondslaw.inventionIonInorganic ChemistryMetalO ligandslawElectron paramagnetic resonanceBridging ligands010405 organic chemistryChemistryHydrogen bondStructure elucidation[CHIM.MATE]Chemical Sciences/Material chemistryCopper0104 chemical sciencesDensity functional calculationsCrystallographyvisual_artvisual_art.visual_art_mediumHydrazone ligandSupramolecular chemistry
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Photomagnetic properties of an Fe(ii) spin-crossover complex of 6-(3,5-diamino-2,4,6-triazinyl)-2,2'-bipyridine and its insertion into 2D and 3D bime…

2017

International audience; The Fe(ii) complex of the L1 ligand (L1 = 6-(3,5-diamino-2,4,6-triazinyl)-2,2'-bipyridine) has been used as a templating cation for the growth of oxalate-based networks. The magnetic characterization of the [Fe(II)(L1)2](ClO4)2·CH3CN (1) precursor in the solid state has been performed for the first time showing that the low-spin (LS) state is predominating from 2 to 400 K with 10% of Fe(ii), which undergoes a gradual and irreversible spin-crossover above 350 K. 1 presents the LIESST effect with a photo-conversion close to 25% and a T(LIESST) of 49 K. During the preparation of 1, a secondary product of the formula [Fe(II)(L1)(CH3CN)2(H2O)](ClO4)2·CH3CN (2) has been ob…

010405 organic chemistryLigandStereochemistrySolid-state[CHIM.MATE]Chemical Sciences/Material chemistry010402 general chemistry01 natural sciencesOxalateLIESST22'-Bipyridine0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistrySpin crossoverBimetallic strip
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Reversible switching of the electronic ground state in a pentacoordinated Cu(ii) complex.

2013

International audience; An easy reversible switching of the electronic ground state in a pentacoordinated copper(ii) complex is reported for the first time. The simple protonation of a carboxylic group in a Cu(ii) complex with a {dx(2)-y(2)}(1) electronic configuration leads to a flip of the ground electronic configuration from {dx(2)-y(2)}(1) to {dz(2)}(1) in the metal ion.

Carboxylic groupMolecular Conformationchemistry.chemical_elementInorganic compoundsElectronsProtonationCrystallography X-Ray010402 general chemistry01 natural sciencesCatalysisMetalCoordination ComplexesComputational chemistryElectronic ground stateMaterials Chemistry010405 organic chemistryChemistryMetals and AlloysGeneral Chemistry[CHIM.MATE]Chemical Sciences/Material chemistryCopper3. Good health0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsReversible switchingvisual_artCeramics and Compositesvisual_art.visual_art_mediumQuantum TheoryPhysical chemistryElectron configurationGround stateCopper
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Switching and redox isomerism in first-row transition metal complexes containing redox active Schiff base ligands.

2014

International audience; The reversible redox isomerisms in first row transition metal complexes of the type ML2 were studied. The six ML2 complexes (M = Mn(III) (), Fe(II) (), Co(III) (), Ni(II) (), Cu(II) () and Zn(II) ()) were synthesized with a redox active Schiff base ligand [2-(3,5-di-tert-butyl-2-hydroxyphenylamino)-4-chlorophenol] (H3L) presenting different oxidation states from -2 to 0 (L(2-), L(-) and L(0)). EPR spectra and magnetic susceptibility measurements indicate the presence of complexes of the type [Mn(III)(L(2-))(L(-))] () with S = 1/2, [Fe(II)(L(-))2] () with S = 2, [Co(III)(L(2-))(L(-))] () with S = 1/2, [Ni(II)(L(-))2] () with S = 1, [Cu(II)(L(-))2] () with S = 1/2 and …

010402 general chemistryLigands01 natural sciencesRedoxlaw.inventionInorganic Chemistrychemistry.chemical_compoundElectron transferTransition metalIsomerismlawCoordination ComplexesMetals HeavyElectron paramagnetic resonanceSchiff BasesValence (chemistry)Schiff base010405 organic chemistryLigand[CHIM.MATE]Chemical Sciences/Material chemistryTautomer0104 chemical sciences3. Good healthCrystallographychemistryOxidation-Reduction
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Spin-crossover compounds based on iron(II) complexes of 2,6-bis(pyrazol-1-yl)pyridine (bpp) functionalized with carboxylic acid and ethyl carboxylic …

2018

International audience; Four new salts of the iron(II) complex of the 2,6-bis(pyrazol-1-yl)pyridine ligand functionalized with a carboxylic acid group (bppCOOH) of formulas [Fe(bppCOOH)2](BF4)2 (1(BF4)2), [Fe(bppCOOH)2](CF3SO3)2·yMe2CO (1(CF3SO3)2·yMe2CO), [Fe(bppCOOH)2](AsF6)2·yMe2CO (1(AsF6)2·yMe2CO) and [Fe(bppCOOH)2](SbF6)2·yMe2CO (1(SbF6)2·yMe2CO) have been prepared and characterized together with a more complete structural and photomagnetic characterization of the previously reported [Fe(bppCOOH)2](ClO4)2 (1(ClO4)2). Furthermore, the iron(II) complex of the ethyl ester derivative of bppCOOH (bppCOOEt) has been prepared and characterized (compound [Fe(bppCOOEt)2](ClO4)2·yMe2CO, 2(ClO4)…

chemistry.chemical_classification010405 organic chemistryLigandCarboxylic acidSpin transition[CHIM.MATE]Chemical Sciences/Material chemistryQuímica010402 general chemistry01 natural sciencesMedicinal chemistryLIESST0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundchemistrySpin crossoverPyridineÀcids carboxílicsCompostos de coordinacióIsostructuralDerivative (chemistry)
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Effect of metal dilution on the light-induced spin transition in [FexZn1-x(phen)2(NCS)2] (phen = 1,10-phenanthroline)

2008

International audience; The thermal and light-induced spin transitions in [FexZn1-x(phen)2(NCS)2] (phen = 1,10-phenantholine) have been investigated by magnetic susceptibility, photomagnetism and diffuse reflectivity measurements. These complexes display a thermal spin transition and undergo the light-induced excited spin state trapping (LIESST) effect at low temperatures. For each compound, the thermal spin transition temperature, T1/2, and the relaxation temperature of the photo-induced high-spin state, T(LIESST), have been systematically determined. It appears that T1/2 decreases with the metal dilution while T(LIESST) remains unchanged. This behaviour is discussed on the basis of the ki…

Spin statesPhenanthrolineAnalytical chemistrySpin transition010402 general chemistry01 natural sciencesLIESSTInorganic ChemistryMagnetic susceptibilitychemistry.chemical_compoundChemical compoundsDiffuse reflectivity measurements010405 organic chemistryMetalRelaxation (NMR)[CHIM.MATE]Chemical Sciences/Material chemistryPhotomagnetismMagnetic susceptibility3. Good health0104 chemical scienceschemistryExcited statePhysical chemistryCondensed Matter::Strongly Correlated ElectronsLIESSTPhotomagnetism
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Insertion of a [Fe II (pyimH) 3 ] 2+ [pyimH = 2‐(1 H ‐Imidazol‐2‐yl)pyridine] Spin‐Crossover Complex Inside a Ferromagnetic Lattice Based on a Chiral…

2015

The insertion of the [FeII(pyimH)3]2+ [pyimH = 2-(1H-imidazol-2-yl)pyridine] spin-crossover complex into a ferromagnetic bimetallic oxalate network affords the hybrid compound [FeII(pyimH)3][MnIICrIII(ox)3]2·X (ox = C2O42–). This spin-crossover complex templates the growth of crystals formed by a chiral 3D oxalate network. The magnetic properties of this hybrid magnet show the coexistence of long-range ferromagnetic ordering at 4.5 K and a spin crossover of the intercalated [FeII(pyimH)3]2+ complex above 250 K. The compound presents a light-induced excited spin-state trapping (LIESST) effect below 60 K although with limited photoconversion (less than 8 %).

Inorganic chemistry02 engineering and technology010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesLIESSTOxalate0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographychemistryFerromagnetismSpin crossoverExcited statePyridine0210 nano-technologyChirality (chemistry)Bimetallic stripEuropean Journal of Inorganic Chemistry
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A hybrid magnet with coexistence of ferromagnetism and photoinduced Fe(iii) spin-crossover

2011

International audience; The insertion of a [Fe(sal2-trien)]+ complex cation into a 2D oxalate network results in a hybrid magnet with coexistence of magnetic ordering and photoinduced spin-crossover (LIESST effect) in compound [FeIII(sal2-trien)][MnIICrIII(ox)3]*(CH2Cl2) (1). A complete photomagnetic characterization together with a detailed structural analysis of the low-spin (LS) and high-spin (HS) structures of 1 is presented in order to understand such unusual behavior. This very rare and unexpected property in a FeIII spin-crossover complex, has been attributed to the strong distortion exhibited by the metastable HS state. Furthermore, 1 has shown that, in contrast to what has been pre…

010405 organic chemistryChemistryStereochemistry[CHIM.MATE]Chemical Sciences/Material chemistryGeneral Chemistry010402 general chemistry01 natural sciencesLIESSTOxalate0104 chemical scienceschemistry.chemical_compoundCrystallographyFerromagnetismSpin crossoverMetastabilityMagnetSpin (physics)Chemical Science
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An investigation of photo- and pressure-induced effects in a pair of isostructural two-dimensional spin-crossover framework materials

2014

International audience; Two new isostructural iron(II) spin-crossover (SCO) framework (SCOF) materials of the type [Fe(dpms)2 (NCX)2 ] (dpms=4,4'-dipyridylmethyl sulfide; X=S (SCOF-6(S)), X=Se (SCOF-6(Se))) have been synthesized. The 2D framework materials consist of undulating and interpenetrated rhomboid (4,4) nets. SCOF-6(S) displays an incomplete SCO transition with only approximately 30 % conversion of high-spin (HS) to low-spin iron(II) sites over the temperature range 300-4 K (T1/2 =75 K). In contrast, the NCSe(-) analogue, SCOF-6(Se), displays a complete SCO transition (T1/2 =135 K). Photomagnetic characterizations reveal quantitative light- induced excited spin-state trapping (LIES…

010405 organic chemistryChemistryIronOrganic ChemistrySpin transitionMineralogyGeneral Chemistry[CHIM.MATE]Chemical Sciences/Material chemistryAtmospheric temperature range010402 general chemistrySpin crossover01 natural sciencesCatalysisLIESST0104 chemical sciencesCoordination polymersChalcogenCrystallographySpin crossoverExcited stateMetastabilityMagnetic propertiesChalcogensIsostructural
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Photomagnetic properties of an Iron(II) low-spin complex with an unusually long-lived metastable LIESST state

2007

A comprehensive study of the photomagnetic behavior of the [Fe(L222N5)(CN)2].H2O complex has been carried out. This complex is characterized by a low-spin (LS) iron(II)-metal center up to 400 K and exhibits at 10 K the well-known Light-Induced Excited Spin State Trapping (LIESST) effect. The critical LIESST temperature (T(LIESST)) has been measured to be 105 K. The kinetics of the transition from the metastable high-spin (HS) state to the low-spin state have been determined and used for reproducing the experimental T(LIESST) curve. This study represents a second example of a fully low-spin iron(II)-metal complex up to 400 K, which can be photoexcited at low temperature with an atypical long…

Coordination sphereSpin states010405 organic chemistryChemistryKineticsCyanideTrappingMacrocyclic Schiff-base ligand[CHIM.MATE]Chemical Sciences/Material chemistryIron complexes010402 general chemistry01 natural sciencesLIESST0104 chemical sciencesInorganic ChemistryCrystallographyComputational chemistryExcited stateMetastabilityLIESSTPhysical and Theoretical ChemistrySpin (physics)
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Effect of the metal dilution on the thermal and light-induced spin transition in [FexMn1−x(bpp)2](NCSe)2: When T(LIESST) reaches T1/2

2008

International audience; The thermal and light-induced spin transition in [FexMn1−x(bpp)2](NCSe)2 (bpp = 2,6-bis(pyrazol-3-yl)pyridine) has been investigated by magnetic susceptibility, photomagnetism and diffuse reflectivity measurements. These complexes display a thermal spin transition and exhibit the light-induced excited spin state trapping (LIESST) effect at low temperature. For each mixed-crystal system, the thermal spin transition temperature, T1/2, and the relaxation temperature of the photo-induced high-spin state, T(LIESST), have been systematically determined. It appears that T1/2 decreases with the metal dilution while T(LIESST) remains unchanged, suggesting that the two interco…

Ligand field theoryCondensed matter physicsSpin states010405 organic chemistryChemistryRelaxation (NMR)Spin transition[CHIM.MATE]Chemical Sciences/Material chemistry010402 general chemistryPhotomagnetismSpin crossover01 natural sciencesMagnetic susceptibilityLIESST0104 chemical sciencesCoordination chemistryInorganic ChemistrySpin crossoverMaterials ChemistryPhysical chemistryPhysical and Theoretical ChemistryMetal dilutionPhotomagnetism
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Influence of Metal Dilution on the Light‐Induced Spin Transition in Two 1D Chain Compounds: [Fe x Zn 1– x (btzp) 3 ](BF 4 ) 2 and [Fe x Zn 1– x (endi…

2008

The thermal and light-induced spin transitions in [FexZn1–x(btzp)3](BF4)2 and [FexZn1–x(endi)3](BF4)2 {btzp = 1,2-bis(tetrazol-1-yl)propane; endi = 1,2-bis(tetrazol-1-yl)ethane} chain compounds have been investigated by magnetic susceptibility, photomagnetism and diffuse reflectivity measurements. These compounds display a thermal spin transition and the Light-Induced Excited Spin State Trapping (LIESST) effect at low temperature. For each compound, the thermal spin transition temperature, T1/2, and the relaxation temperature of the photo-induced high-spin state, T(LIESST), have been systematically determined. A decrease in T1/2 induces an increase in T(LIESST). The results are discussed an…

Spin states010405 organic chemistryChemistryRelaxation (NMR)Spin transition010402 general chemistryPhotomagnetism01 natural sciencesMagnetic susceptibilityLIESST0104 chemical sciencesInorganic ChemistryNuclear magnetic resonanceSpin crossoverExcited statePhysical chemistryEuropean Journal of Inorganic Chemistry
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Structural, thermal and photomagnetic properties of spin crossover [Fe(bpp)2]2+ salts bearing [Cr(L)(ox)2]- anions

2009

International audience; This paper is divided into two parts: in the first part, the influence of solvate molecules on the magnetic properties of spin crossover salts of [Fe(bpp)(2)][Cr(L)(ox)(2)]ClO(4) x nS (bpp = 2,6-bis(pyrazol-3yl)pyridine; L = 2,2'-bipyridine (bpy) or 1,10-phenanthroline (phen); ox = oxalate dianion; S = solvent) is analyzed. The second part is devoted to the photomagnetic properties of the previously reported [Fe(bpp)(2)][Cr(L)(ox)(2)](2) family of compounds. The study describes the crystal structure, differential scanning calorimetry (DSC) and magnetic properties of [Fe(bpp)(2)][Cr(bpy)(ox)(2)]ClO(4) x EtOH x 4 H(2)O (1) and [Fe(bpp)(2)][Cr(phen)(ox)(2)]ClO(4) x 1.5 …

education.field_of_study010405 organic chemistryChemistryPopulationCrystal structure[CHIM.MATE]Chemical Sciences/Material chemistry010402 general chemistry01 natural sciencesLIESSTOxalate0104 chemical sciencesInorganic ChemistryCrystallographychemistry.chemical_compoundNuclear magnetic resonanceDifferential scanning calorimetrySpin crossoverPyridineMoleculeeducation
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Magnetostructural correlations in CuII−NC−WV linkage: the case of [CuII(diimine)]2+−[WV(CN)8]3− 0D assemblies

2009

International audience; We report on the syntheses, crystal structures, and magnetic properties of two cyano-bridged molecular assemblies: [CuII(phen)3]2{[CuII(phen)2]2[WV(CN)8]2}(ClO4)2·10H2O (phen = 1,10-phenanthroline) (1) and {[CuII(bpy)2]2[WV(CN)8]} {[CuII(bpy)2][WV(CN)8]}·4H2O (bpy = 2,2′-bipyridyl) (2). Compound 1 consists of cyano-bridged [CuII2WV2]2− molecular rectangles and isolated [CuII(phen)3]2+ complexes. The molecular structure of 2 reveals cyano-bridged trinuclear [CuII2WV]+ and dinuclear [CuIIWV]− ions. Magnetic interactions in 1 are interpreted in terms of the model of a tetranuclear moiety consisting of two ferromagnetic CuII−NC−WV units (J1 = +39(4) cm−1) interacting ant…

010405 organic chemistryStereochemistryChemistryCrystal structureCrystal structureMagnetic response[CHIM.MATE]Chemical Sciences/Material chemistry010402 general chemistry01 natural sciencesAntiferromagnetic coupling0104 chemical sciencesIonInorganic ChemistryCrystallographyFerromagnetismTheoryofComputation_ANALYSISOFALGORITHMSANDPROBLEMCOMPLEXITYMagnetic propertiesMoleculeMoietyChemical synthesisPhysical and Theoretical ChemistryCyano bridged molecular assembliesDiimine
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Stimuli responsive hybrid magnets : tuning the photoinduced spin-crossover in Fe(III) complexes inserted into layered magnets

2013

The insertion of a [Fe(sal_2 trien)]^+ complex cation into a 2D oxalate network in the presence of different solvents results in a family of hybrid magnets with coexistence of magnetic ordering and photoinduced spin crossover (LIESST effect) in compounds [Fe^{III}(sal_2 trien)][Mn^{II}Cr^{III}(ox)_3]·CHCl_3 (1·CHCl_{3}) [Fe^{III}(sal_{2} trien)][Mn^{II}Cr^{III}(ox)_{3}]·CHBr_{3} (1·CHBr_{3}) and [Fe^{III}(sal_{2} trien)][Mn^{II}Cr^{III}(ox)_{3}]·CH_{2}Br_{2} (1·CH_{2}Br_{2}). The three compounds crystallize in a 2D honeycomb anionic layer formed by Mn^{II} and Cr^{III} ions linked through oxalate ligands and a layer of [Fe(sal_{2} trien)]^{+} complexes and solvent molecules (CHCl_{3} CHBr_{…

MagnetismInorganic chemistry010402 general chemistry01 natural sciencesBiochemistryCatalysisOxalateLIESSTchemistry.chemical_compoundColloid and Surface ChemistrySpin crossoverFe(III)Mössbauer spectroscopyOrganometallic CompoundsMoleculeMolecular Structure010405 organic chemistryChemistryRelaxation (NMR)Complex cationMagnetismHybrid magnetsGeneral ChemistryOxalate network[CHIM.MATE]Chemical Sciences/Material chemistryPhotochemical Processes0104 chemical sciencesCrystallographyMagnetic FieldsFerromagnetismddc:540Solvents
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CCDC 1856807: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographybis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(hexafluoroarsenate) acetone solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 921248: Experimental Crystal Structure Determination

2014

Related Article: Ashok Sasmal, Eugenio Garribba, Carlos J. Gómez-García, Cédric Desplanches, Samiran Mitra|2014|Dalton Trans.|43|15958|doi:10.1039/C4DT01699H

(2-(35-Di-t-butyl-2-oxophenylamino)-4-chlorophenolato radical dianion)-(2-(35-di-t-butyl-2-oxophenylamino)-4-chlorophenolato)-cobalt(iii)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 921246: Experimental Crystal Structure Determination

2014

Related Article: Ashok Sasmal, Eugenio Garribba, Carlos J. Gómez-García, Cédric Desplanches, Samiran Mitra|2014|Dalton Trans.|43|15958|doi:10.1039/C4DT01699H

Space GroupCrystallographyCrystal System(2-(35-Di-t-butyl-2-oxophenylamino)-4-chlorophenolato radical dianion)-(2-(35-di-t-butyl-2-oxophenylamino)-4-chlorophenolato)-manganese(iii) acetonitrile solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 929206: Experimental Crystal Structure Determination

2014

Related Article: Miguel Clemente-León, Eugenio Coronado, Maurici López-Jordà, João C. Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean-François Létard, Andreas Hauser , and Antoine Tissot|2013|J.Am.Chem.Soc.|135|8655|doi:10.1021/ja402674x

Space GroupCrystallographyCrystal Systemcatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-iron) hexakis(mu~2~-oxalato)-tetra-chromium chloroform solvate)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 929201: Experimental Crystal Structure Determination

2014

Related Article: Miguel Clemente-León, Eugenio Coronado, Maurici López-Jordà, João C. Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean-François Létard, Andreas Hauser , and Antoine Tissot|2013|J.Am.Chem.Soc.|135|8655|doi:10.1021/ja402674x

Space GroupCrystallographyCrystal Systemcatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-iron(iii)) hexakis(mu2-oxalato)-di-chromium(iii)-di-manganese(ii) dibromomethane solvate)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1856804: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

bis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(tetrafluoroborate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1856814: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) diperchlorateExperimental 3D Coordinates
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CCDC 929203: Experimental Crystal Structure Determination

2014

Related Article: Miguel Clemente-León, Eugenio Coronado, Maurici López-Jordà, João C. Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean-François Létard, Andreas Hauser , and Antoine Tissot|2013|J.Am.Chem.Soc.|135|8655|doi:10.1021/ja402674x

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-iron(iii)) hexakis(mu2-oxalato)-di-chromium(iii)-di-manganese(ii) bromoform solvate)Experimental 3D Coordinates
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CCDC 1411200: Experimental Crystal Structure Determination

2015

Related Article: Maurici López-Jordà, Mónica Giménez-Marqués, Cédric Desplanches, Guillermo Mínguez Espallargas, Miguel Clemente-León, Eugenio Coronado|2016|Eur.J.Inorg.Chem.||2187|doi:10.1002/ejic.201500790

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[tris(2-(1H-Imidazol-2-yl)pyridine)-iron(ii) bis(tris(mu2-oxalato)-chromium(iii)-manganese(ii)) dihydrate]Cell ParametersExperimental 3D Coordinates
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CCDC 1856808: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

bis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(hexafluoroantimonate) acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 929204: Experimental Crystal Structure Determination

2014

Related Article: Miguel Clemente-León, Eugenio Coronado, Maurici López-Jordà, João C. Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean-François Létard, Andreas Hauser , and Antoine Tissot|2013|J.Am.Chem.Soc.|135|8655|doi:10.1021/ja402674x

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-iron) hexakis(mu~2~-oxalato)-tetra-chromium bromoform solvate)Experimental 3D Coordinates
researchProduct

CCDC 1856805: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

bis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(tetrafluoroborate)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1856813: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographyCrystal Systembis[ethyl 26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylate]-iron(ii) diperchlorate acetone solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1856809: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographyCrystal Systembis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(trifluoromethanesulfonate) acetone solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 929205: Experimental Crystal Structure Determination

2014

Related Article: Miguel Clemente-León, Eugenio Coronado, Maurici López-Jordà, João C. Waerenborgh, Cédric Desplanches, Hongfeng Wang, Jean-François Létard, Andreas Hauser , and Antoine Tissot|2013|J.Am.Chem.Soc.|135|8655|doi:10.1021/ja402674x

Space GroupCrystallographyCrystal Systemcatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-iron) hexakis(mu~2~-oxalato)-tetra-chromium chloroform solvate)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1856812: Experimental Crystal Structure Determination

2018

Related Article: Miguel Clemente Leon, Víctor García-López, Mario Palacios-Corella, Alexandre Abhervé, Isaac Pellicer-Carreño, Cédric Desplanches, Eugenio Coronado|2018|Dalton Trans.|47|16958|doi:10.1039/C8DT03511C

Space GroupCrystallographyCrystal Systembis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(trifluoromethanesulfonate) acetone solvateCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 984617: Experimental Crystal Structure Determination

2014

Related Article: Ashok Sasmal, Eugenio Garribba, Carlos J. Gómez-García, Cédric Desplanches, Samiran Mitra|2014|Dalton Trans.|43|15958|doi:10.1039/C4DT01699H

(2-(35-Di-t-butyl-2-oxophenylamino)-4-chlorophenolato radical dianion)-(2-(35-di-t-butyl-2-oxophenylamino)-4-chlorophenolato)-cobalt(iii)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1856811: Experimental Crystal Structure Determination

2018

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bis[26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylic acid]-iron(ii) bis(hexafluoroantimonate) acetone solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 921249: Experimental Crystal Structure Determination

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Space GroupCrystallographyCrystal SystemCrystal Structurebis(2-(35-Di-t-butyl-2-oxophenylamino)-4-chlorophenolato)-nickel(ii) methanol solvateCell ParametersExperimental 3D Coordinates
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CCDC 1856810: Experimental Crystal Structure Determination

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Space GroupCrystallographyCrystal Systembis[ethyl 26-bis(1H-pyrazol-1-yl)pyridine-4-carboxylate]-iron(ii) diperchlorate acetone solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1856806: Experimental Crystal Structure Determination

2018

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CCDC 929202: Experimental Crystal Structure Determination

2014

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Space GroupCrystallographycatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-iron) hexakis(mu~2~-oxalato)-tetra-chromium dibromomethane solvate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 929207: Experimental Crystal Structure Determination

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Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(bis((22'-(25811-Tetraazadodeca-111-diene-112-diyl)diphenolato)-iron) hexakis(mu~2~-oxalato)-tetra-chromium dichloromethane solvate)Experimental 3D Coordinates
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CCDC 929208: Experimental Crystal Structure Determination

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Space GroupCrystallographycatena-(bis((22'-(25811-Tetra-azadodeca-111-diene-112-diyl)diphenolato)-gallium) hexakis(mu2-oxalato)-tetra-chromium dichloromethane solvate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 921247: Experimental Crystal Structure Determination

2014

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