6533b826fe1ef96bd1283c32
RESEARCH PRODUCT
Reversible switching of the electronic ground state in a pentacoordinated Cu(ii) complex.
Reum ScottAntonio BauzáAshok SasmalSandeepta SahaCarlos J. Gómez-garcíaSamiran MitraEugenio GarribbaRay J. ButcherCédric DesplanchesAntonio Fronterasubject
Carboxylic groupMolecular Conformationchemistry.chemical_elementInorganic compoundsElectronsProtonationCrystallography X-Ray010402 general chemistry01 natural sciencesCatalysisMetalCoordination ComplexesComputational chemistryElectronic ground stateMaterials Chemistry010405 organic chemistryChemistryMetals and AlloysGeneral Chemistry[CHIM.MATE]Chemical Sciences/Material chemistryCopper3. Good health0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsReversible switchingvisual_artCeramics and Compositesvisual_art.visual_art_mediumQuantum TheoryPhysical chemistryElectron configurationGround stateCopperdescription
International audience; An easy reversible switching of the electronic ground state in a pentacoordinated copper(ii) complex is reported for the first time. The simple protonation of a carboxylic group in a Cu(ii) complex with a {dx(2)-y(2)}(1) electronic configuration leads to a flip of the ground electronic configuration from {dx(2)-y(2)}(1) to {dz(2)}(1) in the metal ion.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-07-26 |