0000000000594547

AUTHOR

Reum Scott

0000-0003-2737-6414

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Reversible switching of the electronic ground state in a pentacoordinated Cu(ii) complex.

2013

International audience; An easy reversible switching of the electronic ground state in a pentacoordinated copper(ii) complex is reported for the first time. The simple protonation of a carboxylic group in a Cu(ii) complex with a {dx(2)-y(2)}(1) electronic configuration leads to a flip of the ground electronic configuration from {dx(2)-y(2)}(1) to {dz(2)}(1) in the metal ion.

Carboxylic groupMolecular Conformationchemistry.chemical_elementInorganic compoundsElectronsProtonationCrystallography X-Ray010402 general chemistry01 natural sciencesCatalysisMetalCoordination ComplexesComputational chemistryElectronic ground stateMaterials Chemistry010405 organic chemistryChemistryMetals and AlloysGeneral Chemistry[CHIM.MATE]Chemical Sciences/Material chemistryCopper3. Good health0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsReversible switchingvisual_artCeramics and Compositesvisual_art.visual_art_mediumQuantum TheoryPhysical chemistryElectron configurationGround stateCopper
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CCDC 881999: Experimental Crystal Structure Determination

2013

Related Article: Ashok Sasmal,Sandeepta Saha,Carlos J. Gomez-Garcia,Cedric Desplanches,Eugenio Garribba,Antonio Bauza,Antonio Frontera,Reum Scott,Ray J. Butcher,Samiran Mitra|2013|Chem.Commun.|49|7806|doi:10.1039/C3CC44276D

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu2-Chloro)-bis(2-((1-(pyridin-2-yl)ethylidene)amino)terephthalato)-di-copper(ii) monohydrateExperimental 3D Coordinates
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