0000000000410882
AUTHOR
Giacalone F.
Covalently Supported Imidazolium Salts In Catalysis
Synthesis and catalytic applications of supported imidazolium salts covalently linked to the proper support are described. As supports here we report, among others, the use of amorphous and mesoporous silica, polyhedral oligomeric silsesquioxanes, magnetic-based silica, polystyrenes, halloysite nanotubes, carbon nanoforms such as fullerenes, carbon nanotubes, carbon nanohorns, graphene. The catalytic applications have been divided into two main sections, metal-free based and metal-based reactions.
Reverse electrodialysis – Multi effect distillation heat engine fed by lithium chloride solutions
Salinity Gradient Heat Engines (SG-HEs) have been proposed as a promising technology for converting low-temperature heat into electricity. The SG-HE includes two different processes: (i) a salinity gradient process where the salinity gradient between two solutions is converted into electricity and (ii) a thermal regeneration process where low-grade heat (T<100°C) is used to re-establish the original salinity gradient of the two streams. Among the proposed working solutions, aqueous solution of lithium chloride has been identified as one of the most promising thanks to its remarkable solubility and activity. In this work, a process model to study the performance of a SG-HE constituted by …